1. A preparation method of a glass PMMA micro-nano interface structure laminated material is characterized by comprising the following steps: comprises the following steps;

the method comprises the following steps: putting 20-30 parts of PMMA particles and 70-80 parts of ABS highlight particles into a reaction kettle, heating to a molten state, adding a certain component of antioxidant and initiator, and stirring and mixing at 150-200 ℃ for 50-60 min to obtain a raw material a;

step two, mixing and stirring organosilane, deionized water, an organic solvent, a low surface tension solvent and a catalyst to obtain a gel, and performing centrifugal drying on the gel obtained in the step two in a microgravity environment to obtain aerogel;

step three, putting 5-8 parts of aerogel into a reaction kettle, stirring and mixing the aerogel with the raw material a, and adding a compatilizer and a fixing agent with certain components to obtain a raw material b;

placing the mixture raw material b in a conventional glass smelting furnace, and obtaining the nanoporous glass according to a conventional glass manufacturing process method;

step five, preparing TiO2 powder, acetone, PE, PVB and the like into suspension in an ultrasonic generator according to a certain proportion and adding sequence;

and step six, placing the nanoporous glass obtained in the step four into the suspension prepared in the step 5, and carrying out heat treatment polymerization in a high-pressure nitrogen atmosphere to prepare the glass/PMMA laminated material with the micro-nano interface structure.

2. The preparation method of the glass PMMA micro-nano interface structure laminated material according to claim 1, which is characterized by comprising the following steps: the antioxidant can be antioxidant 1010 or antioxidant 1076 as main antioxidant, and antioxidant 168 as auxiliary antioxidant.

3. The preparation method of the glass PMMA micro-nano interface structure laminated material according to claim 1, which is characterized by comprising the following steps: the initiator is any one of azobisisobutyronitrile, azobisisoheptonitrile, dialkyl peroxide and dibenzoyl peroxide.

4. The preparation method of the glass PMMA micro-nano interface structure laminated material according to claim 1, which is characterized by comprising the following steps: the compatilizer is one of styrene grafted maleic anhydride or ethylene-methyl acrylate copolymer.

5. The preparation method of the glass PMMA micro-nano interface structure laminated material according to claim 1, which is characterized by comprising the following steps: the fixing agent is any one or more of osmium tetroxide, formaldehyde, glutaraldehyde and uranium acetate.

6. The preparation method of the glass PMMA micro-nano interface structure laminated material according to claim 1, which is characterized by comprising the following steps: the preparation of the suspension comprises the following steps:

s1: putting 10-20 parts of TiO2 powder into a container, adding 15-20 parts of acetone solution into the container, and stirring and mixing;

s2: and adding 2-5 parts of PE solution and 0.5-1 part of PVB powder into the container, stirring again, and pouring the fully stirred solution into an ultrasonic generator to prepare suspension.

Background

Polymethyl methacrylate (PMMA) is a high molecular polymer, also called as acrylic or organic glass, has the advantages of high transparency, low price, easy machining and the like, and is a glass substitute material frequently used in the prior art;

nanotechnology (nanotechnology) is a scientific technology for manufacturing substances by using single atoms and molecules, and researches the properties and application of materials with the structure size ranging from 1 to 100 nanometers, the current research and application of nanotechnology mainly aims at the aspects of materials and preparation, microelectronics and computer technology, medicine and health, aerospace and aviation, environment and energy, biotechnology and agricultural products and the like, the equipment manufactured by using the nanomaterials has lighter weight, stronger hardness, longer service life, lower maintenance cost and more convenient design, and the nanomaterials can be used for manufacturing materials with specific properties or materials which do not exist in the natural world to manufacture biomaterials and bionic materials;

the invention is especially provided in view of the fact that the nano technology is integrated with organic glass for manufacturing, the overall performance of the glass can be improved, the organic glass can be more conveniently cleaned and is anti-aging due to the nano material, and the strength and the service life of the organic glass can be improved.

Disclosure of Invention

The invention aims to provide a preparation method of a glass PMMA micro-nano interface structure laminated material, which aims to solve the problems in the background technology.

In order to achieve the purpose, the invention provides the following technical scheme: a preparation method of a glass PMMA micro-nano interface structure laminated material is characterized by comprising the following steps: comprises the following steps;

the method comprises the following steps: putting 20-30 parts of PMMA particles and 70-80 parts of ABS highlight particles into a reaction kettle, heating to a molten state, adding a certain component of antioxidant and initiator, and stirring and mixing at 150-200 ℃ for 50-60 min to obtain a raw material a;

step two, mixing and stirring organosilane, deionized water, an organic solvent, a low surface tension solvent and a catalyst to obtain a gel, and performing centrifugal drying on the gel obtained in the step two in a microgravity environment to obtain aerogel;

step three, putting 5-8 parts of aerogel into a reaction kettle, stirring and mixing the aerogel with the raw material a, and adding a compatilizer and a fixing agent with certain components to obtain a raw material b;

placing the mixture raw material b in a conventional glass smelting furnace, and obtaining the nanoporous glass according to a conventional glass manufacturing process method;

step five, preparing TiO2 powder, acetone, PE, PVB and the like into suspension in an ultrasonic generator according to a certain proportion and adding sequence;

and step six, placing the nanoporous glass obtained in the step four into the suspension prepared in the step 5, and carrying out heat treatment polymerization in a high-pressure nitrogen atmosphere to prepare the glass/PMMA laminated material with the micro-nano interface structure.

Preferably, the antioxidant can be antioxidant 1010 or antioxidant 1076 as a main antioxidant, and antioxidant 168 as an auxiliary antioxidant.

Preferably, the initiator is any one of azobisisobutyronitrile, azobisisoheptonitrile, dialkyl peroxide and dibenzoyl peroxide.

Preferably, the compatilizer is one of styrene grafted maleic anhydride or ethylene-methyl acrylate copolymer.

Preferably, the fixing agent is any one or combination of more of osmium tetroxide, formaldehyde, glutaraldehyde and uranium acetate.

Preferably, the preparation of the suspension comprises the following steps:

s1: putting 10-20 parts of TiO2 powder into a container, adding 15-20 parts of acetone solution into the container, and stirring and mixing;

s2: and adding 2-5 parts of PE solution and 0.5-1 part of PVB powder into the container, stirring again, and pouring the fully stirred solution into an ultrasonic generator to prepare suspension.

The preparation method of the glass PMMA micro-nano interface structure laminated material has the beneficial effects that:

the glass/PMMA laminated material with the micro-nano interface structure can be prepared by mixing aerogel with certain components with the raw material a to obtain a raw material b, obtaining nano-pore glass from the raw material b according to a conventional glass manufacturing process method, and performing heat treatment polymerization on the suspension liquid again.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Embodiment 1, the present invention provides a technical solution: a preparation method of a glass PMMA micro-nano interface structure laminated material is characterized by comprising the following steps: comprises the following steps;

the method comprises the following steps: putting 25 parts of PMMA particles and 75 parts of ABS highlight particles into a reaction kettle, heating to a molten state, adding 5 parts of antioxidant 1010 and 6 parts of azobisisobutyronitrile, and stirring and mixing at 180 ℃ for 50min to obtain a raw material a;

step two, mixing and stirring organosilane, deionized water, an organic solvent, a low surface tension solvent and a catalyst to obtain a gel, and performing centrifugal drying on the gel obtained in the step two in a microgravity environment to obtain aerogel;

step three, putting 8 parts of aerogel into a reaction kettle, stirring and mixing the aerogel with the raw material a, and adding 10 parts of styrene grafted maleic anhydride and 8 parts of mixed solvent of formaldehyde and glutaraldehyde to obtain a raw material b;

placing the mixture raw material b in a conventional glass smelting furnace, and obtaining the nanoporous glass according to a conventional glass manufacturing process method;

step five, comprising the following steps:

s1: putting 15 parts of TiO2 powder into a container, adding 20 parts of acetone solution into the container, and stirring and mixing;

s2: adding 5 parts of PE solution and 0.8 part of PVB powder into the container, stirring again, and pouring the fully stirred solution into an ultrasonic generator to prepare suspension;

and step six, placing the nanoporous glass obtained in the step four into the suspension prepared in the step 5, and carrying out heat treatment polymerization in a high-pressure nitrogen atmosphere to prepare the glass/PMMA laminated material with the micro-nano interface structure.

Embodiment 2, the present invention provides a technical solution: a preparation method of a glass PMMA micro-nano interface structure laminated material is characterized by comprising the following steps: comprises the following steps;

the method comprises the following steps: putting 25 parts of PMMA particles and 80 parts of ABS highlight particles into a reaction kettle, heating to a molten state, adding 6 parts of main antioxidant 1076, 3 parts of auxiliary antioxidant 168 and 9 parts of azobisisobutyronitrile, and stirring and mixing at 150 ℃ for 50min to obtain a raw material a;

step two, mixing and stirring organosilane, deionized water, an organic solvent, a low surface tension solvent and a catalyst to obtain a gel, and performing centrifugal drying on the gel obtained in the step two in a microgravity environment to obtain aerogel;

step three, putting 7 parts of aerogel into a reaction kettle, stirring and mixing the aerogel with the raw material a, and adding 10 parts of ethylene-methyl acrylate copolymer and 10 parts of mixed solvent of formaldehyde and glutaraldehyde to obtain a raw material b;

placing the mixture raw material b in a conventional glass smelting furnace, and obtaining the nanoporous glass according to a conventional glass manufacturing process method;

step five, comprising the following steps:

s1: putting 18 parts of TiO2 powder into a container, adding 18 parts of acetone solution into the container, and stirring and mixing;

s2: adding 3 parts of PE solution and 1 part of PVB powder into the container, stirring again, and pouring the fully stirred solution into an ultrasonic generator to prepare suspension;

and step six, placing the nanoporous glass obtained in the step four into the suspension prepared in the step 5, and carrying out heat treatment polymerization in a high-pressure nitrogen atmosphere to prepare the glass/PMMA laminated material with the micro-nano interface structure.

Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.