1. The utility model provides a microscope needle point for regulation and control of near field area light field, includes the needle point body, the needle point body is the triangular prism form, and its top surface is isosceles triangle shape, its characterized in that, needle point body outward appearance is equipped with the non-axisymmetric micro-nano structure who is used for changing magnetic field distribution that comprises the different material metallic film of multi-disc.

2. The microscope tip for near-field region light field manipulation according to claim 1, wherein each metal film is made of one of Au, Ag, Cu, Al, Mg, Pt, Yb.

3. The microscope needle tip for near-field region light field regulation and control according to claim 1, wherein the non-axisymmetric micro-nano structure comprises a first isosceles triangular metal film (2) plated on the top surface of the needle tip body and connected to the tip, and rectangular metal films (1) plated on the two side surfaces of the tip of the needle tip body respectively and fully plated with different materials.

4. The microscope needle tip for near field region light field regulation and control according to claim 1, wherein the non-axisymmetric micro-nano structure comprises a second isosceles triangle metal film (4) plated on the top surface of the needle tip body and connected to the tip, and block metal films (3) respectively plated on two side surfaces of the tip of the needle tip body and connected with the straight line where the tip is located, wherein the block metal films are made of different materials.

5. The microscope needle tip for near field region light field regulation and control of claim 1, wherein the non-axisymmetric micro-nano structure comprises two triangular metal films (5) which are plated on the top surface of the needle tip body and are symmetrically arranged and made of different materials, and the two triangular metal films (5) are connected to the tip end of the needle tip body.

6. The microscope tip for near-field region light field manipulation according to claim 5, wherein the triangular metal film (5) has an isosceles triangle shape, and wherein an angle between a line and a side line connecting the tip end adjacent to the top surface of the tip body is 10-30 °.

7. The microscope needle tip for near field region light field regulation and control of claim 1, wherein the non-axisymmetric micro-nano structure comprises a central metal film (6) plated on the top surface of the needle tip body and side metal films (7) which are symmetrically arranged on two sides of the central metal film and are different in material, the central metal film (6) and the side metal films (7) are in an isosceles triangle shape, and the central metal film (6) and the side metal films (7) are connected to the tip end of the needle tip body.

8. The microscope tip for near-field region light field manipulation according to claim 7, wherein the central metal film (6) midline coincides with the tip body top surface midline, and the included angle between the lateral metal film (7) midline and the adjacent edge line connecting the tip to the tip top surface is 10-30 °.

9. The microscope tip for near-field region light field manipulation according to any one of claims 5 to 8, wherein both side surfaces connected to the tip of the tip body are not plated with a metal film or are plated with metal films of the same material.

10. A preparation method of a microscope needle tip for near field region light field regulation is characterized in that the preparation method is used for preparing a needle tip with a non-axisymmetric micro-nano structure, and comprises the following steps:

s1, preparing a triangular prism-shaped near-field optical microscope needle tip;

s2, plating metal films of different materials on the top surface of the near-field optical microscope needle tip and the side surface connected with the tip end of the needle tip in a vacuum evaporation mode, or plating more than two metal films of different materials on the top surface of the needle tip, so that the needle tip has a non-axisymmetric micro-nano structure.

11. The method for preparing a microscope tip for near-field optical field manipulation according to claim 10, wherein in step S2, the material of each metal film is one of Au, Ag, Cu, Al, Mg, Pt, Yb.

12. The method for preparing a microscope tip for near-field light field manipulation according to claim 10, wherein step S1 comprises the following sub-steps:

s11, selecting and cleaning the glass main body, and then heating the glass main body to remove the surface moisture of the glass main body;

s12, cleaning pollutants on the glass main body by using a carbon dioxide air gun;

s13, scribing a needle point structure on the surface of the glass main body by using a diamond cutter;

and S14, breaking the glass along the scribing line of the tip structure to obtain the near-field optical microscope tip.

13. The method for preparing a microscope tip for near-field region light field manipulation according to claim 10, wherein the thickness of the metal film is 20-50 nm.

Background

The near-field optical microscope can overcome the defects that the traditional optical microscope has low resolution, and the scanning electron microscope and the scanning tunnel microscope damage biological samples, and the like, so the near-field optical microscope is more and more widely applied, particularly in the fields of biomedicine, nano materials, microelectronics and the like, becomes an optical means for exploring the mysteries of biomacromolecule activities, and brings powerful experimental weapons to biologists.

In the prior art, a near-field optical microscope can be used for super-resolution detection of a printing type organic electroluminescent material; researches show that if the near field region optical field can be more accurately regulated and controlled in super-resolution detection, particularly detection of a microelectronic device based on charge transport behavior can achieve higher detection precision, more accurate detection results can be obtained in the super-resolution detection of a printed organic electroluminescent material, and other researches show that asymmetric distribution of a magnetic field can generate photon spin orbit angular momentum at the near field of a microscope needle point, and the orbit angular momentum generated by photon spin generates torque on transmission electrons; however, the near-field optical microscope tips in the prior art are symmetrically designed, have uniform and symmetric magnetic field distribution, cannot achieve an electronic regulation effect, and restrict higher detection precision in super-resolution detection.

Accordingly, the prior art is yet to be improved and developed.

Disclosure of Invention

In view of the foregoing deficiencies of the prior art, an object of the embodiments of the present application is to provide a microscope tip for near field optical field modulation and a method for manufacturing the same, so as to obtain an electromagnetic field at the modulated tip to change a local angular momentum of the tip, so as to change a transmission direction characteristic of electrons in molecules, and improve a detection accuracy of super-resolution detection.

First aspect, this application embodiment provides a microscope needle point for regulation and control of near field area light field, including the needle point body, the needle point body is the triangular prism form, and its top surface is isosceles triangle shape, needle point body outward appearance is equipped with the non-axisymmetric micro-nano structure who is used for changing magnetic field distribution that comprises the different material metallic film of multi-disc.

The microscope needle point for near field region light field regulation and control in the embodiment of the application regulates and controls a magnetic field distribution structure at the needle point through a non-axisymmetric micro-nano structure, further controls the effect of the local angular momentum of the needle point in electron transmission, and can be applied to super-resolution detection of a printing type organic electroluminescent material to obtain higher detection precision.

The microscope needle tip for near field region light field regulation and control is characterized in that each metal film is made of one of Au, Ag, Cu, Al, Mg, Pt and Yb.

The microscope needle point for near field region light field regulation and control, wherein, the non-axisymmetric micro-nano structure including plate in needle point body top surface and connect in most advanced first isosceles triangle-shaped metal film to and plate respectively in needle point body most advanced both sides side and plate the rectangle metal film that the material is different.

The microscope needle point for near field region light field regulation and control, wherein, the non-axisymmetric micro-nano structure including plate in needle point body top surface and connect in sharp second class waist triangle-shaped metal film to and plate respectively in the sharp both sides side of needle point body and with the different bulk metal film of the material of sharp point place sharp junction.

The microscope needle point for near field region light field regulation and control, wherein, the non-axisymmetric micro-nano structure includes two triangular metal films plated on the top surface of the needle point body and different in material arranged symmetrically, and the two triangular metal films are connected to the tip end of the needle point body.

The microscope needle tip for near field region light field regulation and control is characterized in that the triangular metal film is in an isosceles triangle shape, and an included angle between a line of the triangular metal film and a side line, connected to the tip end, of the adjacent needle tip body top surface is 10-30 degrees.

The microscope needle point for near field region light field regulation and control, wherein, non-axisymmetric micro-nano structure including plate in the central authorities metallic film of needle point body top surface with respectively the symmetrical side metallic film that is located well metallic film both sides and material difference, central authorities metallic film with the side metallic film all is isosceles triangle shape, central authorities metallic film and side metallic film all connect in needle point body point.

The microscope needle tip for near field region light field regulation and control is characterized in that the central line of the central metal film is superposed with the central line of the top surface of the needle tip body, and the included angle between the central line of the side metal film and the side line, connected to the tip end, of the top surface of the adjacent needle tip body is 10-30 degrees.

The microscope needle tip for near field light field regulation and control is characterized in that two side surfaces connected to the tip end of the needle tip body are not plated with metal films or are plated with metal films with the same materials.

In a second aspect, an embodiment of the present application further provides a method for preparing a microscope tip for near field light field modulation, which is used for preparing a tip having a non-axisymmetric micro-nano structure, and the method includes the following steps:

s1, preparing a triangular prism-shaped near-field optical microscope needle tip;

s2, plating metal films of different materials on the top surface of the near-field optical microscope needle tip and the side surface connected with the tip end of the needle tip in a vacuum evaporation mode, or plating more than two metal films of different materials on the top surface of the needle tip, so that the needle tip has a non-axisymmetric micro-nano structure.

The preparation method in the embodiment of the application can be used for quickly and conveniently preparing the near-field optical microscope needle point with the non-axisymmetric micro-nano structure, and can be applied to super-resolution detection of the printed organic electroluminescent material to obtain higher detection precision.

The preparation method of the microscope needle tip for near field region light field regulation comprises the step S2, wherein each metal film is made of one of Au, Ag, Cu, Al, Mg, Pt and Yb.

The preparation method of the microscope tip for near field light field regulation comprises the following steps of S1:

s11, selecting and cleaning the glass main body, and then heating the glass main body to remove the surface moisture of the glass main body;

s12, cleaning pollutants on the glass main body by using a carbon dioxide air gun;

s13, scribing a needle point structure on the surface of the glass main body by using a diamond cutter;

and S14, breaking the glass along the scribing line of the tip structure to obtain the near-field optical microscope tip.

The preparation method of the microscope needle tip for near field light field regulation is characterized in that the thickness of the metal film is 20-50 nm.

Therefore, the microscope needle point for near field region light field regulation and control and the preparation method thereof provided by the embodiment of the application can be used for quickly and conveniently preparing the near field optical microscope needle point with the non-axisymmetric micro-nano structure, the needle point regulates and controls the magnetic field distribution structure at the needle point through the non-axisymmetric micro-nano structure, further the action of the local angular momentum of the needle point in electron transmission is controlled, and the method can be applied to super-resolution detection of a printing type organic electroluminescent material to obtain higher detection precision.

Drawings

In order to more clearly illustrate the technical solutions of the embodiments of the present application, the drawings that are required to be used in the embodiments of the present application will be briefly described below, it should be understood that the following drawings only illustrate some embodiments of the present application and therefore should not be considered as limiting the scope, and that those skilled in the art can also obtain other related drawings based on the drawings without inventive efforts.

Fig. 1 is a partial structural schematic diagram of a near-field optical microscope tip according to embodiment 1 of the present application.

Fig. 2 is a partial structural schematic diagram of a near-field optical microscope tip according to embodiment 2 of the present application.

Fig. 3 is a partial structural schematic diagram of a near-field optical microscope tip according to embodiment 3 of the present application.

Fig. 4 is a partial structural schematic diagram of a near-field optical microscope tip according to embodiment 4 of the present application.

FIG. 5 is a diagram showing the magnetic field distribution of a conventional tip.

Fig. 6 is a diagram showing the magnetic field distribution of the near field optical microscope tip according to example 1 of the present application.

Fig. 7 is a diagram showing the magnetic field distribution of the near field optical microscope tip according to example 2 of the present application.

Fig. 8 is a diagram showing the magnetic field distribution of the near field optical microscope tip according to example 3 of the present application.

Fig. 9 is a diagram showing the magnetic field distribution of the near field optical microscope tip according to example 4 of the present application.

Fig. 10 is a surface topography of a printed organic electroluminescent material printed HTL obtained by using the conventional tip of example 1 in super-resolution detection.

Fig. 11 is a surface topography diagram of a printed organic electroluminescent material printed with the printed organic electroluminescent material obtained by using the near-field optical microscope tip in super-resolution detection in example 1 of the present application.

Reference numerals: 1. a rectangular metal film; 2. a first isosceles triangular metal film; 3. a bulk metal film; 4. a second isosceles triangular metal film; 5. a triangular metal film; 6. a central metal film; 7. a side metal film.

Detailed Description

The technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the drawings in the embodiments of the present application, and it is obvious that the described embodiments are only a part of the embodiments of the present application, and not all of the embodiments. The components of the embodiments of the present application, generally described and illustrated in the figures herein, can be arranged and designed in a wide variety of different configurations. Thus, the following detailed description of the embodiments of the present application, presented in the accompanying drawings, is not intended to limit the scope of the claimed application, but is merely representative of selected embodiments of the application. All other embodiments, which can be derived by a person skilled in the art from the embodiments of the present application without making any creative effort, shall fall within the protection scope of the present application.

In a first aspect, the embodiment of the application provides a microscope needle tip for near field region light field regulation and control, including the needle tip body, the needle tip body is the triangular prism form, and its top surface is isosceles triangle shape, and the needle tip body outward appearance is equipped with the non-axisymmetric micro-nano structure who is used for changing magnetic field distribution that comprises the metal film of multiple different materials.

The non-axisymmetric micro-nano structure refers to an asymmetric structure of a metal film caused by material difference, so that the needle tip body can generate non-axisymmetric magnetic field distribution.

The needle point in the embodiment of the application can be used for regulating and controlling the magnetic field distribution structure at the needle point through the non-axisymmetric micro-nano structure so as to control the effect of the local angular momentum of the needle point in electronic transmission, and can be applied to super-resolution detection of a printing type organic electroluminescent material to obtain higher detection precision.

Specifically, the microscope needle tip for near field region light field regulation and control provided by the embodiment of the application is provided with a non-axisymmetric micro-nano structure, and the metal films made of different materials in the non-axisymmetric micro-nano structure are utilized to influence the magnetic field distribution on the needle tip body. In a more detailed way, the local magnetic field of the needle tip can generate local angular momentum due to asymmetry and couple to nearby molecules, so that a photon spin coupling system can be regulated and controlled by changing the structure of the needle tip to control the distribution of the magnetic field, further the action of the local angular momentum of the needle tip in electron transmission is controlled, and higher detection precision can be obtained in the super-resolution detection of the printed organic electroluminescent material.

In some preferred embodiments, the material of each metal film is one of Au, Ag, Cu, Al, Mg, Pt, Yb, etc., and the material of the corresponding metal film can be selected according to the actual requirement and the position and shape of the metal film.

In some preferred embodiments, the non-axisymmetric micro-nano structure is mainly divided into the following four coating modes.

As shown in fig. 1, the first coating method generates the following non-axisymmetric micro-nano structure: the non-axisymmetric micro-nano structure comprises a first isosceles triangular metal film 2 plated on the top surface of the needle point body and connected to the tip end, and rectangular metal films 1 plated on the two side surfaces of the tip end of the needle point body respectively and plated with different materials; the first isosceles triangular metal film 2 on the top surface of the needle tip body is used as a base body for generating a near-field electromagnetic field, and the rectangular metal films 1 on the side surfaces of the two sides of the tip are made of different metal materials, so that the near-field electromagnetic field distribution based on the first isosceles triangular metal film 2 is influenced, and the non-axisymmetric magnetic field distribution based on the first isosceles triangular metal film 2 is generated, so that a photon spin coupling system can be regulated and controlled by controlling the magnetic field distribution, the effect of the local angular momentum of the needle tip in electronic transmission is further controlled, and higher detection precision can be obtained in the super-resolution detection of the printed organic electroluminescent material.

In some preferred embodiments, the center line of the first isosceles triangular metal film 2 coincides with the center line of the top surface of the isosceles triangle of the tip body, so that the generated magnetic field is distributed non-axisymmetrically with respect to the center line of the top surface.

As shown in fig. 2, the second coating method generates the following non-axisymmetric micro-nano structure: the non-axisymmetric micro-nano structure comprises a second isosceles triangular metal film 4 plated on the top surface of the needle point body and connected to the tip end, and block-shaped metal films 3 which are plated on the two side surfaces of the tip end of the needle point body respectively and are connected with the straight line where the tip end is located and are made of different materials; the second isosceles triangular metal film 4 on the top surface of the needle tip body is used as a base body for generating a near-field electromagnetic field, and the blocky metal films 3 on the two side surfaces of the tip end are made of different metal materials, so that the near-field electromagnetic field distribution based on the second isosceles triangular metal film 4 is influenced, and the non-axisymmetric magnetic field distribution based on the second isosceles triangular metal film 4 is generated, so that a photon spin coupling system can be regulated and controlled by controlling the magnetic field distribution, the effect of the local angular momentum of the needle tip in electron transmission is further controlled, and higher detection precision can be obtained in the super-resolution detection of the printed organic electroluminescent material.

In some preferred embodiments, the bulk metal film 3 is circular and tangent to the line of the tip, and in other embodiments may be triangular, elliptical, parallelogram, etc.

In certain preferred embodiments, the rounded bulk metal membrane 3 is tangent to the adjacent top surface border of the needle tip body.

In some preferred embodiments, the central line of the second isosceles triangular metal film 4 coincides with the central line of the isosceles triangular top surface of the needle tip body, so that the generated magnetic field is distributed non-axisymmetrically with respect to the central line of the top surface.

As shown in fig. 3, the third coating method generates the following non-axisymmetric micro-nano structure: the non-axisymmetric micro-nano structure comprises two triangular metal films 5 which are plated on the top surface of the needle point body and are symmetrically arranged and made of different materials, and the two triangular metal films 5 are connected to the tip end of the needle point body; the two triangular metal films 5 on the top surface are used as a substrate for generating a near-field electromagnetic field, and different metal materials are adopted for the two triangular metal films 5, so that the near-field electromagnetic field distribution of the top surface of the needle tip body is influenced, and non-axisymmetric magnetic field distribution taking a symmetry axis between the two triangular metal films 5 as a reference is generated, so that a photon spin coupling system can be regulated and controlled by controlling the magnetic field distribution, the effect of the local angular momentum of the needle tip in electron transmission is further controlled, and higher detection precision can be obtained in the super-resolution detection of the printed organic electroluminescent material.

In certain preferred embodiments, the two triangular metal films 5 do not overlap each other, ensuring the magnetic field distribution to be ordered.

In some preferred embodiments, the two triangular metal films 5 are symmetrically disposed with respect to the center line of the isosceles triangular top surface of the needle tip body as the symmetry axis, so that the generated magnetic field is distributed non-axisymmetrically with respect to the center line of the top surface.

In some preferred embodiments, the triangular metal film 5 has an isosceles triangle shape, and the angle between the line and the adjacent side line connecting the tip end of the tip body top surface is 10-30 °.

In some preferred embodiments, since the metal film plated on the top surface of the needle tip body has the effect of non-axisymmetric distribution of the magnetic field, the two side surfaces of the tip of the needle tip body can adopt a form of symmetric plating, i.e., both side surfaces connected to the tip of the needle tip body are not plated with the metal film or are plated with the same metal film.

As shown in fig. 4, the fourth coating method generates the following non-axisymmetric micro-nano structure: the non-axisymmetric micro-nano structure comprises a central metal film 6 plated on the top surface of the needle point body and side metal films 7 which are symmetrically positioned on two sides of the central metal film and are made of different materials, wherein the central metal film 6 and the side metal films 7 are in isosceles triangle shapes, and the central metal film 6 and the side metal films 7 are connected to the tip end of the needle point body; the central metal film 6 and the side metal films 7 on the top surface of the needle tip body are used as substrates for generating near-field electromagnetic fields, the side metal films 7 on the two sides of the central metal film 6 are made of different metal materials, so that the near-field electromagnetic field distribution with the central metal film 6 as the center is influenced, non-axisymmetric magnetic field distribution with the central metal film 6 as the reference is generated, a photon spin coupling system can be regulated and controlled by controlling the magnetic field distribution, the effect of the local angular momentum of the needle tip in electron transmission is further controlled, and higher detection precision can be obtained in the super-resolution detection of the printing type organic electroluminescent material.

In some preferred embodiments, the midline of the central metal film 6 coincides with the midline of the tip body top surface, and the included angle between the midline of the side metal film 7 and the adjacent side line of the tip body top surface connected to the tip is 10-30 degrees.

In certain preferred embodiments, the central line of the central metal film 6 coincides with the central line of the top surface of the isosceles triangle shape of the tip body, so that the generated magnetic field is distributed non-axisymmetrically with respect to the central line of the top surface.

In some preferred embodiments, the central metal film 6 and the side metal films 7 do not overlap each other, ensuring ordered magnetic field distribution.

In some preferred embodiments, since the metal film plated on the top surface of the needle tip body has the effect of non-axisymmetric distribution of the magnetic field, the two side surfaces of the tip of the needle tip body can adopt a form of symmetric plating, i.e., both side surfaces connected to the tip of the needle tip body are not plated with the metal film or are plated with the same metal film.

It is worth mentioning that, in the actual coating process, the tip is only coated on the top surface near the tip, so that fig. 1-4 are enlarged partial top views of the corresponding tip near the tip.

The embodiment of the application discloses various near-field optical microscope needle points with non-axisymmetric micro-nano structures formed by a plurality of metal films made of different materials on the outer surfaces and used for changing the distribution of a magnetic field, which are used for regulating and controlling a photon spin coupling system, controlling the action of the local angular momentum of the needle points in electron transmission and obtaining higher detection precision in the super-resolution detection of a printing type organic electroluminescent material.

In a second aspect, an embodiment of the present application further provides a method for preparing a microscope tip for near field light field modulation, which is used for preparing a tip having a non-axisymmetric micro-nano structure, and the method includes the following steps:

s1, preparing a triangular prism-shaped near-field optical microscope needle tip;

and S2, plating metal films with different materials on the top surface of the near-field optical microscope needle tip and the side surface connected with the tip of the needle tip in a vacuum evaporation mode, or plating more than two metal films with different materials on the top surface of the needle tip, so that the needle tip has a non-axisymmetric micro-nano structure.

The preparation method in the embodiment of the application can be used for quickly and conveniently preparing the near-field optical microscope needle point with the non-axisymmetric micro-nano structure, and can be applied to super-resolution detection of the printed organic electroluminescent material to obtain higher detection precision.

In some preferred embodiments, in step S2, different forms of non-axisymmetric micro-nano structures may be generated according to different coating manners, such as:

1. the needle point comprises a first isosceles triangle metal film 2 and rectangular metal films 1, wherein the first isosceles triangle metal film 2 is positioned on the top surface of a needle point body and connected to the tip end, and the rectangular metal films 1 are fully plated on the two side surfaces of the tip end of the needle point body and are made of different materials;

2. the second isosceles triangle metal film 4 is positioned on the top surface of the needle point body and connected with the tip end, and the block metal films 3 which are respectively positioned on the two side surfaces of the tip end of the needle point body and are connected with the straight line where the tip end is positioned and are made of different materials;

3. the two triangular metal films 5 are symmetrically arranged on the top surface of the needle tip body and are made of different materials, and the two triangular metal films 5 are connected to the tip end of the needle tip body.

4. The metal film 6 and the side metal film 7 that the material is different in the metal film both sides and in the symmetry respectively that are located needle point body top surface, central metal film 6 and side metal film 7 all are isosceles triangle shape, and central metal film 6 and side metal film 7 all connect in the needle point body pointed end.

In some preferred embodiments, in step S2, the material of each metal film is one of Au, Ag, Cu, Al, Mg, Pt, and Yb, and the material of the corresponding metal film can be selected according to the actual requirement and the position and shape of the metal film.

In certain preferred embodiments, step S1 includes the following sub-steps:

s11, selecting a proper glass main body, cleaning the surface of the glass main body, and then heating the glass main body to remove the surface moisture of the glass main body;

s12, cleaning pollutants on the glass main body by using a carbon dioxide air gun to generate a dry high-speed carbon dioxide airflow;

s13, scribing a needle point structure on the surface of the glass main body by using a diamond cutter;

and S14, breaking the glass along the scribing line of the tip structure to obtain the near-field optical microscope tip.

In certain preferred embodiments, the metal film has a thickness of 20 to 50nm, which can produce a desired magnetic field distribution without affecting the tip shape structure as much as possible.

In certain preferred embodiments, the heating temperature in step S11 is 310-320K, which can sufficiently remove moisture from the surface of the glass body under milder conditions.

In certain preferred embodiments, step S13 is to first cross-scribe the glass body surface by a diamond cutter, scribe the tip of the tip, and then scribe the front side of the tip laterally to form an isosceles triangular scribe.

The near-field optical microscope needle tip which meets the specification and is dry and clean in surface can be rapidly prepared through the steps S11-14, and the preparation of the near-field optical microscope needle tip with the non-axisymmetric micro-nano structure is facilitated.

The present invention is further illustrated by the following specific examples.

Example 1:

selecting a microscope glass cover slip with the thickness of 0.25mm and the size of 22mm x 22mm as a glass main body, cleaning the surface of the glass cover slip by using water, putting the glass cover slip on a heating plate, and heating to 320K to remove the water on the surface of the glass cover slip;

a carbon dioxide air gun is selected to generate dry high-speed carbon dioxide airflow to clean pollutants on the glass cover glass;

scribing on the surface of the glass by using a diamond cutter after cleaning;

carefully breaking the glass along the scratch to obtain a triangular prism-shaped near-field optical microscope tip;

the top surface of the needlepoint is an isosceles triangle with the bottom side length of 3.292mm and the height of 1.975 mm;

plating a 30nm thick isosceles triangle gold film on the top surface of the needle tip by vacuum evaporation, wherein the height of the triangular film is 553nm, the length of the bottom edge is 100nm, the central line of the gold film is coincided with the central line of the top surface of the needle tip, and the top point of the gold film is coincided with the needle tip, namely is connected with the tip end of the needle tip;

and finally, plating a rectangular silver film and a rectangular copper film on two side surfaces of the tip of the needle tip respectively, wherein the thicknesses of the rectangular silver film and the rectangular copper film are both 30nm, and obtaining the near-field optical microscope needle tip with the non-axisymmetric micro-nano structure for changing the magnetic field distribution as shown in figure 1.

Example 2:

a triangular prism-shaped near-field optical microscope needle was prepared in the manner of example 1, the tip top surface being an isosceles triangle having a base side length of 3.292mm and a height of 1.975 mm;

and plating a 30nm thick isosceles triangle gold film on the top surface of the needle tip by vacuum evaporation, wherein the height of the triangular film is 553nm, the length of the bottom edge is 100nm, the central line of the gold film is coincided with the central line of the top surface of the needle tip, and the top point of the gold film is coincided with the needle tip, namely is connected with the tip end of the needle tip.

And finally, plating a circular copper film and a circular silver film on two side surfaces of the tip of the needle point respectively, wherein the thickness of the silver film and the thickness of the copper film are both 30nm, the radius of the silver film and the radius of the copper film are both 150nm, and the circular copper film and the circular silver film are tangent to a straight line where the tip of the needle point is located, so that the near-field optical microscope needle point with the non-axisymmetric micro-nano structure for changing the magnetic field distribution, which is shown in figure 2, is obtained.

Example 3:

a triangular prism-shaped near-field optical microscope needle was prepared in the manner of example 1, the tip top surface being an isosceles triangle having a base side length of 5.372mm and a height of 2.126 mm;

and then, plating a gold film and a copper film which are symmetrically arranged on the top surface of the needle point in a vacuum evaporation mode, wherein the thicknesses of the gold film and the copper film are both 30nm and are in an isosceles triangle shape, the heights of the gold film and the copper film are both 553nm, the bottom side lengths of the gold film and the copper film are both 100nm, the top points of the gold film and the copper film are both coincided with the needle point, namely, the gold film and the copper film are connected to the tip end of the needle point, the gold film and the copper film are symmetrically arranged by taking the central line of the top surface of the needle point as a symmetric axis, and the included angles between the central lines of the gold film and the copper film and the top end side lines of the adjacent side surfaces of the needle point are 20 degrees, so that the near-field optical microscope needle point with the non-axisymmetric micro-nano structure for changing the distribution of the magnetic field as shown in the figure 3 is obtained.

Example 4:

a triangular prism-shaped near-field optical microscope needle was prepared in the manner of example 1, the tip top surface being an isosceles triangle having a base length of 6.252mm and a height of 2.215 mm;

and then plating a gold film, a silver film and a copper film on the top surface of the needle tip in a vacuum evaporation mode, wherein the gold film, the silver film and the copper film are all 30nm thick and in an isosceles triangle shape, the height is 553nm, the bottom side length is 100nm, and the top point is coincided with the needle tip, namely, the gold film, the silver film and the copper film are connected to the tip end of the needle tip, wherein the central line of the gold film is coincided with the central line of the top surface of the needle tip, the silver film and the copper film are symmetrically arranged on two sides of the gold film by taking the central line of the gold film as a symmetry axis, and the included angles between the central lines of the silver film and the copper film and the top end side lines of the adjacent needle tip side are 20 degrees respectively, so that the non-axisymmetric micro-nano structure near-field optical microscope needle tip for changing the magnetic field distribution as shown in figure 4 is obtained.

More specifically, in order to verify whether the needle tip has the characteristics of a regulation photon spin coupling system, the needle tip prepared in the embodiment 1-4 is simulated by adopting an FDTD simulation program, the wavelength of an unpolarized laser light source is 632.8nm, the light is vertically incident from the right upper side of the needle tip, the needle tip prepared in the embodiment 1-4 and a common needle tip with the top surface and two side surfaces being fully plated with gold films are tested, and a magnetic field distribution situation diagram corresponding to the needle tip is obtained; in addition, the magnetic field distribution of the ordinary tip is as shown in FIG. 5, the tip size is the same as that of the tip prepared in example 1, the magnetic field distribution of the ordinary tip has symmetrically distributed magnetic field characteristics, and the magnetic field distribution of the tips prepared in examples 1 to 4 is as shown in FIGS. 6 to 9 in this order.

In the case of the distribution of the magnetic field at the tip of the needle of embodiment 1 shown in fig. 6 and the distribution of the magnetic field at the tip of embodiment 2 shown in fig. 7, it can be seen that the magnetic field intensity distribution at both sides of the tip is significantly asymmetric, and the magnetic field intensity at the left tip is significantly greater than that at the right side within the height range of 100nm to 300nm from the bottom end of the tip. Meanwhile, the magnetic field distribution in the 2nm space range at the lower end of the needle point is asymmetric, the magnetic field distribution area on the left side of the needle point is in the range of minus 50nm in the X-axis direction, the magnetic field distribution area on the right side is in the range of plus 80nm in the X-axis direction, and the magnetic field intensity on the left side is obviously smaller than that on the right side. The magnetic field effect at the bottom end of the tip of example 1 is weaker than that of the tip of example 2.

In the case of the magnetic field distribution at the tip of the embodiment 3 shown in fig. 8 and the magnetic field distribution at the tip of the embodiment 4 shown in fig. 9, it can be seen that the magnetic field intensity at the tip is stronger in the height range of 150nm to 280nm from the bottom end of the tip, the energy distribution is gradually weakened from the intensity center to the outside, and the overall intensity distribution is asymmetric about the central line. The left magnetic field intensity distribution area is within the range of X axis to 220nm, and the right magnetic field intensity distribution area is within the range of X axis to 260 nm. The magnetic field distribution in the 2nm space range at the lower end of the needle point is asymmetric, the magnetic field distribution area at the left side of the needle point is in the range of-150 nm in the X-axis direction, the magnetic field distribution area at the right side is in the range of 220nm in the X-axis direction, and the magnetic field intensity at the right side is smaller than that at the left side. The tip of example 4 had a stronger effect on the magnetic field at the bottom end of the tip than the tip of example 3.

From these two sets of comparison results, the change of the tip structure of the 4 embodiments changes the magnetic field distribution at the tip, so that the magnetic field distribution is adjusted from symmetrical distribution to asymmetrical distribution, which shows that the tip of the embodiments can generate local angular momentum.

More specifically, in order to verify whether the near-field optical microscope tip with the non-axisymmetric micro-nano structure for changing the magnetic field distribution can improve the detection precision in the super-resolution detection of the printing type organic electroluminescent material, the embodiment of the application performs the following experimental detection:

the experiment is super-resolution detection with a printed organic electroluminescent material PEDOT, PSS as an object; the method comprises the steps of placing a Hole Transport Layer (HTL) structure printed by PEDOT (PEDOT: PSS) materials below a needle point, applying a voltage of 0.5V in detection, irradiating the needle point by introducing laser, forming a near-field super-resolution detection image, then transforming different needle points to detect surface topography under the condition of ensuring that materials and other detection conditions are unchanged, and finally comparing topography pictures obtained by adopting different needle points to judge the difference of detection precision.

More specifically, in the examples of the present application, a comparison test was performed using a common metal clad glass tip, i.e., a normal tip, of the same size, and the tip prepared in example 1.

PSS material HTL surface topography after printing is obtained by replacing the needle point for detection, wherein the needle point is shown in FIGS. 10 and 11, FIG. 11 is a detection result of the needle point prepared in the embodiment 1, the scale bar is 0.2nm, the detected surface topography is clear and visible in lines, and a fine surface roughness structure can be observed; fig. 10 is a graph showing the result of measurement using a general tip having the same size as the tip prepared in example 1, and the obtained surface topography is blurred on the same scale of 0.2 nm.

Therefore, the near-field optical microscope needle point with the non-axisymmetric micro-nano structure for changing the magnetic field distribution, which is prepared by the embodiment of the application, can regulate the magnetic field distribution structure at the needle point through the needle point structure, further control the effect of the local angular momentum of the needle point in electronic transmission, can obtain higher detection precision in the super-resolution detection of the printed organic electroluminescent material, and has great potential in the super-resolution detection of the printed organic electroluminescent material.

It is to be understood that the invention is not limited to the examples described above, but that modifications and variations may be effected thereto by those of ordinary skill in the art in light of the foregoing description, and that all such modifications and variations are intended to be within the scope of the invention as defined by the appended claims.