1. A method of making a coated glove having micropores in a surface thereof, comprising:

s1, dipping or coating a pre-prepared rubber material on the glove blank to make the surface of the glove blank hang a layer of rubber material to obtain a rubberized glove blank;

s2, dipping the rubberized glove blank into an aqueous foam treatment agent to enable the rubber material surface of the glove blank to adhere foam, wherein the aqueous foam treatment agent is obtained by dissolving a surfactant in water, mechanically foaming and adjusting viscosity;

s3, soaking the rubberized glove blanks processed in the step S2 into defoaming solution, so that foams adhered to the surface of rubber materials of the glove blanks are quickly exploded under the defoaming action of the defoaming solution, and a plurality of microporous structures are formed on the surface of the rubber materials of the glove blanks;

s4, drying and vulcanizing the rubberized glove blank with the surface provided with the micropore structure and subjected to the S3 treatment.

2. The method of claim 1, wherein in S1, the glove blank is a knitted glove blank, a cotton glove blank, or a flannelette glove blank; when the glove blank is a knitted glove blank, a latex coagulant is dipped before the sizing material to prevent gel permeation during sizing material dipping.

3. The method according to claim 1, wherein in S1, the rubber compound is one or more of a pre-vulcanized natural latex rubber compound, a pre-vulcanized nitrile latex rubber compound, a pre-vulcanized chloroprene latex rubber compound, a pre-vulcanized butyl latex rubber compound, a pre-vulcanized aqueous polyurethane latex rubber compound and a pre-vulcanized ethylene propylene diene monomer rubber compound; the viscosity of the compound was 500-6000 cP.

4. The method according to claim 2, characterized in that the compound is a non-foamed compound or a foamed compound, the foamed compound having a foaming ratio of 1 to 6.

5. The method according to claim 1, wherein in S2, the aqueous foam treatment agent is formulated with soft water; the surfactant in the aqueous foam treating agent is one or more of anionic surfactant, nonionic surfactant, amphoteric surfactant and cationic surfactant.

6. The method according to claim 1, wherein the aqueous foam treatment agent has a foaming ratio of 1 to 6 times and a viscosity of 50 to 3000cP in S2.

7. The method according to claim 1 or 6, wherein in S2, the aqueous foam treatment agent is prepared by mixing and mechanically foaming a surfactant, water and a thickener; the soaking time of the rubberized glove blank in the aqueous foam treatment agent is 1-20 s.

8. The method according to claim 1, wherein the defoaming solution in S3 is an alcohol solution of an organic acid, an alcohol solution of a divalent metal salt, an aqueous solution of an organic acid, an aqueous solution of a divalent metal salt, a solution of an organic acid dissolved in a mixed solvent of water and alcohol, or a solution of a divalent metal salt dissolved in a mixed solvent of water and alcohol.

9. The method for preparing the glove blank according to claim 1, wherein the step S1 is a step of dipping the glove blank twice, the glove blank is pre-dried to 4-8 dry after being dipped for one time, the glove blank is dipped for two times, and the glove blank dipped for two times is transferred to the step S2; the sizing material dipped for the first time is non-foaming sizing material, and the sizing material dipped for the second time is foaming sizing material.

10. A coated glove having surface micro-pores, which is prepared by the method of any one of claims 1 to 9.

Background

The preparation method of the coated glove is generally a dipping method, and the basic process is as follows: preparing latex slurry with certain viscosity, then sleeving a glove blank (knitted fabric or cotton fabric and the like) on a hand mould, dipping the glove blank into the latex slurry by the movement of the hand mould, then taking out the hand mould, coating glue on the glove blank, adjusting the angle of the hand mould to drip glue and homogenize the glue, drying, and finally vulcanizing at high temperature to solidify the coated glue. However, the glue layer on the surface of many coated gloves is hard and astringent, the surface is smooth, and especially in the working environment with low temperature or greasy dirt, the wearing comfort and the anti-skid performance of the gloves are poor, and the gripping performance is poor. In order to improve the gripping sensitivity of the glove, the friction coefficient of the glove surface needs to be increased to increase the anti-slip effect of the glove, and the application range is expanded.

The conventional technology of the antiskid coating glove comprises the following steps: embossing, salt/water mist spraying, surface treatment, and the like. The embossing method needs to open the die in advance, and an embossing groove is formed in the template, so that the method is relatively complicated, the die opening cost is high, and the use of the embossing method is limited because the hand die is a simulated three-dimensional hand die (non-planar hand die), and only partial embossing can be performed on the gloves. The salt spraying method is mainly characterized in that granular salt is sprayed on the surface of the glove which is just soaked with the slurry, and then the salt is washed away after being dried to a certain degree. The method has the advantages of large water consumption, poor production environment and no environmental protection, and can only produce frosted gloves generally. The water spray method can improve the production environment, but the water consumption is large and causes rubber waste, the water spray control difficulty is large, the hanging rubber on the surface of the glove is washed off in a large amount under the condition of poor control, and the rubber layer of the glove is too thin and has poor quality. The surface treating agent method is that the unvulcanized rubber layer on the surface of the dipped glove blank is subjected to the combined action of strong swelling agents such as kerosene, formic acid, ethanol and the like and a rubber coagulant, so that the rubber layer becomes swollen and is coagulated to form the wrinkled glove. The method uses a large amount of organic solvents, is slightly harmful to human bodies, is highly volatile and flammable, has poor production environment, is not environment-friendly, and has certain potential safety hazard.

Disclosure of Invention

Technical problem to be solved

In view of the above-mentioned drawbacks and deficiencies of the prior art, the present invention is directed to a method for making a coated glove with micro-pores on the surface thereof, so as to increase the slip resistance and softness (reduce the feeling of hardness and astringency), improve the wearing comfort, improve the production environment, make the production process more environment-friendly, and make the production quality of the glove more stable and controllable.

(II) technical scheme

In order to achieve the purpose, the invention adopts the main technical scheme that:

in a first aspect, the present invention provides a method of making a coated glove having surface micropores, comprising:

s1, dipping or coating a pre-prepared rubber material on the glove blank to make the surface of the glove blank hang a layer of rubber material to obtain a rubberized glove blank;

s2, dipping the rubberized glove blank into an aqueous foam treatment agent to enable the rubber material surface of the glove blank to adhere foam, wherein the aqueous foam treatment agent is obtained by dissolving a surfactant in water, mechanically foaming and adjusting viscosity;

s3, soaking the rubberized glove blanks processed in the step S2 into defoaming solution, so that foams adhered to the surface of rubber materials of the glove blanks are quickly exploded under the defoaming action of the defoaming solution, and a plurality of microporous structures are formed on the surface of the rubber materials of the glove blanks;

s4, drying and vulcanizing the rubberized glove blank with the surface provided with the micropore structure and subjected to the S3 treatment.

According to a preferred embodiment of the present invention, in S1, the glove blank is a knitted glove blank, a cotton glove blank or a flannelette glove blank; when the glove blank is a knitted glove blank, a latex coagulant is dipped before the sizing material to prevent gel permeation during sizing material dipping.

Because the holes of the knitted glove blank are large, if the knitted glove blank is not dipped with the latex coagulant, the knitted glove blank is easy to permeate into the holes due to the pressure action of the sizing material when being dipped with the sizing material so as to permeate into the inner side surface of the glove blank, and the quality of the glove is influenced. However, the cotton cloth or flannelette glove blank is sewn by cloth materials, and the problem of glue penetration is avoided. In addition, after the glove blank woven by the three-prevention yarn is treated at the temperature of 110-160 ℃ for 3-10min, a large amount of nanoscale lotus leaf-like hydrophobic fluff is raised on the surface of the three-prevention yarn, and under the condition, the three-prevention yarn knitted glove blank is not easy to penetrate glue when being soaked in water-based glue materials and does not need to be soaked in a latex coagulant in advance. Before dipping and coagulating latex, the glove blank is generally heated to 20-80 ℃ (preferably 35-55 ℃) and then dipped into the latex coagulating agent, so that a part of solvent in the latex coagulating agent can be quickly dried and volatilized, and the problem that the glove blank cannot be gelated or the gelated is not uniform due to too much dipping solvent is avoided.

Preferably, the latex coagulant is an aqueous or methanolic solution of calcium or zinc salts, an aqueous or methanolic solution of an organic acid (e.g., formic acid, acetic acid, benzoic acid), an aqueous or methanolic solution of calcium salt + organic acid, or an aqueous or methanolic solution of zinc salt + organic acid.

Preferably, the knitted glove blank is formed by one or more of materials such as terylene, nylon, aramid fiber, ultra-high molecular weight polyethylene, steel wires, bamboo fiber, glass fiber and the like through mixed weaving.

According to a preferred embodiment of the present invention, in S1, the rubber compound is one or more of a pre-vulcanized natural latex rubber compound, a pre-vulcanized nitrile latex rubber compound, a pre-vulcanized chloroprene latex rubber compound, a pre-vulcanized butyl latex rubber compound, a pre-vulcanized aqueous polyurethane latex rubber compound, and a pre-vulcanized ethylene propylene diene monomer rubber compound. The viscosity of the sizing material is designed according to the thickness of the glue layer of the product, the more glue is hung, the larger the thickness of the glue layer of the glove product is, and the viscosity is usually 500-6000cP, preferably 1500-3500 cP.

Preferably, the rubber compound is a foamed rubber compound, namely a foaming agent is added in the rubber compound preparation process; the compound may also be a non-foamed compound. In the case of a foamed rubber compound, the expansion ratio is 1 to 6 times, preferably 1 to 2 times. In the scheme of the invention, under the same other conditions, the foamed rubber material has larger pore diameter, deeper micropores and larger friction coefficient compared with the glove product prepared from the non-foamed rubber material, and the glove product is softer, but the wear resistance and the durability are poor. On the contrary, under the same other conditions, the glove product prepared from the non-foamed rubber material has the advantages of small pore diameter of the microporous structure on the surface, shallow micropores, small friction coefficient, moderate softness, and better wear resistance and durability.

According to a preferred embodiment of the present invention, in S2, the aqueous foam treatment agent is formulated with soft water. Soft water (soft water) refers to water containing no or less soluble calcium and magnesium compounds. Natural soft water generally refers to river water, lake (fresh water lake) water. The softened soft water refers to the softened water obtained after the content of calcium salt and magnesium salt is reduced to 1.0-50 mg/L. The soft water is used for preparing the water-based foam treating agent, so that the use amount of the surfactant can be saved by 50-80%, and the time consumed by mechanical foaming is reduced.

Preferably, the surfactant in the aqueous foam treating agent is one or more of an anionic surfactant, a nonionic surfactant, an amphoteric surfactant and a cationic surfactant; when the size of S1 is an anionic emulsion, a cationic surfactant is preferred in S2, and remains on the surface of the size to promote the setting of the size. The surfactant has a foaming function, and the mechanical foaming mode comprises mechanical stirring foaming or bubbling machine foaming.

Preferably, the anionic surfactant is one or more of dioctyl sodium sulfosuccinate, sodium alkenyl sulfonate, sodium hexadecyl sulfate, sodium octadecyl sulfate, sodium dodecyl benzene sulfonate, peregal and the like. The cationic surfactant is at least one of dodecyl dimethyl benzyl ammonium chloride, tetradecyl trimethyl ammonium chloride, tri (octyl) methyl ammonium chloride and hexadecyl dimethyl ethyl ammonium bromide.

In S2, the foaming ratio and viscosity of the aqueous foam treatment agent are different according to the type of the sizing material (including latex type, foaming or non-foaming) and the specific requirements of the microporous structure of the surface of the glove product. Preferably, the aqueous foam treatment agent has a foaming ratio of 1 to 6 times, preferably a ratio of 2 to 4 times. Under the same other conditions, the larger the expansion ratio, the larger the pore diameter of the micropores on the surface of the glove, and the deeper the pores. If the foaming multiple is about 5, the pore diameter of the micropores on the surface of the glove product is larger than that when the foaming multiple is 3-4 times.

Preferably, the aqueous foam treatment agent also contains a thickening agent for adjusting the viscosity, and the viscosity of the aqueous foam treatment agent is 50-3000cP, preferably 200-1500 cP. Under the same other conditions, the higher the viscosity of the aqueous foam treatment agent, the more the adhesive foam on the rubber surface of the glove blank, the denser the microporous structure on the prepared glove surface, and the larger the roughness.

Specifically, the aqueous foam treatment agent is prepared by mixing and physically foaming a surfactant, water and a thickener. The thickening agent can be added according to the requirement, when the water foam treating agent is in the range of 50-3000cP, the thickening agent can be not added, but a small amount of thickening agent is used in most cases to prevent the water foam treating agent from being too low in viscosity to be adhered to the surface of the sizing material of the glove blank.

In S2, the soaking time of the rubberized glove blank in the aqueous foam treating agent is 1-20S, preferably 5-15S, so as to ensure that more foam adheres to the surface sizing material of the glove blank; however, the soaking time is not longer, the soaking time is longer, the production cycle of the gloves is slowed, the longer soaking time does not bring more foam adhesion, but part of rubber materials fall off and enter the aqueous foam treating agent, the surface rubberizing amount of the gloves is too small, and the quality is unqualified.

According to a preferred embodiment of the present invention, in S3, the defoaming solution is an alcohol solution of an organic acid, an alcohol solution of a divalent metal salt, an aqueous solution of an organic acid, an aqueous solution of a divalent metal salt, a solution of an organic acid dissolved in a mixed solvent of water and alcohol, or a solution of a divalent metal salt dissolved in a mixed solvent of water and alcohol. Wherein the alcohol is a lower alcohol having 1-4 carbon atoms. The organic acid is one or more of formic acid, acetic acid, benzoic acid and phenylacetic acid. Wherein, the concentration of the organic acid in the solution containing the organic acid is 6 to 15 percent; in the solution containing divalent metal salt, if calcium nitrate, calcium chloride or zinc chloride is selected, the concentration is 2-10%. The defoaming liquid is preferably an alcohol solution, and the alcohol is contacted with the sizing material to promote gel solidification and prevent the sizing material from being washed away.

According to the preferred embodiment of the present invention, step S1 may be a double dipping step, in which the glove blank is pre-dried to 4-8 days after the first dipping step, and then the second dipping step is performed, and the glove blank after the second dipping step is transferred to step S2.

According to the preferred embodiment of the present invention, in S1, the rubber material subjected to the first gum dipping is a non-foamed rubber material, and the rubber material subjected to the second gum dipping is a foamed rubber material.

And the primary gum dipping is used for forming a base gum layer of the glove product, the secondary gum dipping is used for forming a surface gum layer, the outer surface of the surface gum layer forms a micropore structure, and the situation that the perforation of the glove gum layer caused by the expansion of foam influences the strength of the glove gum layer when the rubberized glove blank which is only subjected to primary gum dipping is processed in the steps S2-S3 is prevented by virtue of the reinforcing effect of the base gum layer.

The second time of gum dipping is foaming rubber material, the rubber material contains a large amount of bubbles, after the treatment of the steps S2-S3, the bubbles in the outer rubber material are broken by impact due to the bursting of the foams, and the surface of the glove forms a deeper and more microporous structure. Preferably, the rubber material subjected to primary gum dipping is low-viscosity rubber material, and the viscosity of the rubber material subjected to secondary gum dipping is slightly higher than that of the rubber material subjected to primary gum dipping. The lower viscosity of the first-time gum dipping can ensure that the base glue layer is not too thick, so as to control the total thickness of the glue layer of the glove product not to be too large to cause the problem that the wearing flexibility of the glove is poor or the glove is hard and unsmooth. Under the same other conditions, the glove products produced by twice gum dipping have better wear resistance and durability than the gloves dipped once.

When the glove product has no waterproof and oilproof requirements, the treatment of gum dipping at two sides is not needed, and the substrate rubber layer is not needed to be formed. At this time, the viscosity of the rubber material can be set to be moderate, so that after the treatment of the steps S2-S3, the bursting of the foam causes the glove rubber layer to have local micropores and even tiny perforations, and the tiny perforations can ensure that the glove rubber layer has excellent softness and can realize good functions of ventilation, perspiration and heat dissipation. Meanwhile, if the glue material is foam glue, local fine perforations can be formed through the treatment of the steps S2-S3 after one-time glue dipping, and the functions of exhausting air and removing sweat are achieved.

According to the preferred embodiment of the present invention, in S4, the vulcanization temperature is 70-140 ℃, and the vulcanization time can be 1-4 h; preferably, the vulcanization temperature is 90-120 ℃ and the vulcanization time is 1.5-2 h. The vulcanization time and the vulcanization temperature may be specifically set according to the kind of the rubber compound.

In a second aspect, the present invention provides a coated glove having a surface with micropores, the glove being prepared using any of the embodiments described above.

(III) advantageous effects

According to the invention, innovations are made on the process, and the microporous structure is formed on the surface of the glove rubber layer only by using common reagent materials such as a surfactant, a small amount of organic acid, divalent metal salt, alcohol or water and the like, so that the microporous structure brings high friction coefficient and anti-slip property to glove products, the problem that the glove rubber layer is hard and astringent is solved, the glove is softer, the wearing comfort is higher, and the operation is more flexible. In addition, under the condition that fine holes penetrating through the rubber layer are formed in the local microporous structure (the rubber is foamed rubber or is easy to penetrate when the hanging rubber is thin), the glove also has good functions of ventilation, perspiration and dehumidification.

The reagent materials used in the method are very common and easy to obtain, pollution-free, the workshop production environment is good, the distribution density, the aperture depth and the like of micropores on the surface of the glove rubber layer are directly determined by the viscosity of the rubber material, the type (foaming and non-foaming) of the rubber material, the type of the rubber material, the foaming multiple of the aqueous foam treating agent, the viscosity, the soaking time, the type and the concentration of the defoaming solution, and therefore the quality of the glove product produced by the method is stable and controllable. The roughness of the micropores on the surface of the glove prepared by the method is greater than that generated by salt spraying, so that fine slag is not easily abraded in the using process, the wearing environment is not polluted, the wear resistance is good, particularly, the EN388 wear resistance test of the butyronitrile product can reach more than 3 thousands of turns, and the product is far superior to other products in the market.

Drawings

FIG. 1 is a microscopic electron micrograph of the microporous structure of the surface of the glove product prepared in example 1.

FIG. 2 is a microscopic electron micrograph of the microporous structure of the surface of the glove product prepared in example 2.

FIG. 3 is a microscopic electron micrograph of the microporous structure of the surface of the glove product prepared in example 3.

FIG. 4 is a microscopic electron micrograph of the microporous structure of the surface of the glove product prepared in example 4.

Detailed Description

For the purpose of better explaining the present invention and to facilitate understanding, the present invention will be described in detail by way of specific embodiments with reference to the accompanying drawings.

Examples 1 to 4 and 6 to 7 below prepared aqueous foam treatment agents using common industrial tap water, and example 5 prepared aqueous foam treatment agents using soft water.

Example 1

The coated glove with micropores on the surface of the glove is prepared according to the following steps:

(1) dipping the 13-needle polyester glove blank in a methanol solution of calcium chloride with the mass concentration of 2% for 1s, wherein the temperature of the glove blank is 45 ℃.

(2) Dipping the glove blank into natural latex rubber with the foaming times of 1.2 times and the viscosity of 3500cP, extracting, and dripping and homogenizing the rubber to obtain the rubberized glove blank. The natural latex rubber material is prepared and foamed according to a conventional method.

(3) Preparing an aqueous foam treating agent, mechanically stirring and foaming by dodecyl dimethyl benzyl ammonium chloride (cationic surfactant), and adding PVA (thickening agent) for regulation to obtain the aqueous foam treating agent with the foaming times of 3.8 times and the viscosity of 500 cP. And (3) soaking the rubberized glove blanks obtained in the step (2) in the treating agent for 10 seconds, and then extracting.

(4) And (4) soaking the rubberized glove blanks treated in the step (3) in a 10% mass concentration acetic acid methanol solution for 8 seconds.

(5) And (4) drying the semi-finished product treated in the step (4) at 115 ℃ for 2h for vulcanization and drying to obtain the finished product of the natural rubber glove with a large number of micropore structures on the surface.

The gloves are observed under an electron microscope, and an electron microscope image shown in figure 1 is obtained by shooting, and a large number of micropores can be clearly seen from figure 1, wherein part of micropores are closed pits, and part of micropores form deeper pore channels, which is mainly formed by the impregnated rubber compound which is the foamed rubber compound.

Example 2

The coated glove with micropores on the surface of the glove is prepared according to the following steps:

(1) dipping the 13-pin nylon glove blank in a methanol solution of calcium nitrate with the mass concentration of 2.5% for 1s, wherein the temperature of the glove blank is 50 ℃.

(2) And (3) applying nitrile latex rubber with the foaming times of 1.1 times and the viscosity of 3200cP on the surface of the glove blank to obtain the rubberized glove blank. The nitrile latex rubber compound is prepared and foamed according to a conventional method.

(3) Preparing an aqueous foam treating agent, mechanically stirring and foaming by using tetradecyl trimethyl ammonium chloride (cationic surfactant), and adding casein for regulation to obtain the aqueous foam treating agent with the foaming times of 3 times and the viscosity of 500 cP. And (3) soaking the rubberized glove blanks obtained in the step (2) in the treating agent for 10 seconds, and then extracting.

(4) And (4) soaking the rubberized glove blanks treated in the step (3) in a 10% mass concentration formic acid methanol solution for 8 seconds.

(5) And (4) drying the semi-finished product treated in the step (4) at 110 ℃ for 2.5h for vulcanization and drying to obtain the finished nitrile rubber glove product with a large number of micropore structures on the surface.

The glove is observed under an electron microscope, and an electron microscope image as shown in fig. 2 is obtained by shooting, and a large number of micropores can be clearly seen from fig. 2, wherein part of micropores are closed pits, and part of micropores form communicated pore channels, which is mainly formed by the impregnated rubber compound which is the foamed rubber compound.

Example 3

The coated glove with micropores on the surface of the glove is prepared according to the following steps:

(1) dipping the 13-needle nylon/spandex silk glove blank for 1s by using a methanol solution of calcium nitrate with the mass concentration of 2.0%, wherein the temperature of the glove blank is 50 ℃ during dipping.

(2) And (3) applying glue on the surface of the glove blank by adopting a neoprene latex glue stock with the foaming times of 1.2 times and the viscosity of 2800cP to obtain the rubberized glove blank. The neoprene latex sizing material is prepared and foamed according to a conventional method.

(3) Preparing an aqueous foam treating agent, mechanically stirring and foaming by using tetradecyl trimethyl ammonium chloride (cationic surfactant), and adding casein for regulation to obtain the aqueous foam treating agent with the foaming times of 3.4 times and the viscosity of 500 cP. And (3) soaking the rubberized glove blanks obtained in the step (2) in the treating agent for 10 seconds, and then extracting.

(4) And (4) soaking the rubberized glove blanks treated in the step (3) in a 10% mass concentration formic acid methanol solution for 8 seconds.

(5) And (4) drying the semi-finished product treated in the step (4) at 110 ℃ for 2.5h for vulcanization and drying to obtain the finished chloroprene rubber glove product with a large number of microporous structures on the surface.

The glove is observed under an electron microscope, and an electron microscope image as shown in fig. 3 is obtained by shooting, and a large number of micropores can be clearly seen from fig. 3, wherein part of micropores are closed pits, and part of micropores form communicated pore channels, which is mainly formed by the impregnated rubber compound which is the foamed rubber compound.

The cell structure of example 3 has a deeper distribution of cell diameters than that of example 2, but has a shallower distribution than that of example 1, and this is related to the expansion ratio of the aqueous foam treatment agent when the viscosity of the foam treatment agent is the same.

Example 4

The coated glove with micropores on the surface of the glove is prepared according to the following steps:

(1) dipping the 13-needle ultrahigh molecular weight polyethylene and the steel wire glove blank in a methanol solution of 2.5% calcium nitrate for 1s, wherein the temperature of the glove blank is 45 ℃.

(2) And (3) applying nitrile latex rubber material which is not foamed and has the viscosity of 3900cP on the surface of the glove blank to obtain the rubberized glove blank. The nitrile latex rubber compound is prepared according to a conventional method.

(3) Preparing an aqueous foam treating agent, mechanically stirring and foaming by using tri (octyl) methyl ammonium chloride (cationic surfactant), and adding CMC (carboxy methyl cellulose) for regulation to obtain the aqueous foam treating agent with the foaming times of 3.6 times and the viscosity of 600 cP. And (3) soaking the rubberized glove blanks obtained in the step (2) in the treating agent for 10 seconds, and then extracting.

(4) And (4) soaking the rubberized glove blanks treated in the step (3) in 8% of benzoic acid ethanol solution for 10 seconds.

(5) And (4) drying the semi-finished product treated in the step (4) at 120 ℃ for 2.5h for vulcanization and drying to obtain the finished nitrile rubber glove product with a large number of micropore structures on the surface.

The glove was observed under an electron microscope, and an electron micrograph shown in fig. 4 was obtained, and from fig. 4, a large number of micropores were clearly seen, but most of the pores were shallow half-open pores, and few of the pores were interconnected as in example 1. In terms of air permeability, the glove of example 1 has an air permeability of 0.032 under 10MPa after the air permeability test (refer to QB/T-5156-. This is associated with the step (2) of impregnating the size with a non-foamed size. In the embodiment, the cutting-resistant and wear-resistant ultra-high molecular weight polyethylene-steel wire glove blank is used, and the gloves have the performances of wear resistance, cutting resistance, tearing resistance and the like.

Example 5

This example prepares the aqueous foam treatment agent of step (3) using boiling water to cool the resulting soft water on the basis of example 1. In this embodiment, an equivalent amount of the aqueous foam treatment agent with a foaming ratio of 3.8 times is prepared, and the equivalent requirement can be met only by about 1/2 of the amount of the dodecyl dimethyl benzyl ammonium chloride (cationic surfactant) in example 1, and in addition, the pore size of the micropores on the surface of the finally produced glove finished product is closer to the same size and is more uniform when the aqueous foam treatment agent is prepared by using soft water.

Example 6

In this example, in preparing the aqueous foam treatment agent of step (3) based on example 1, the aqueous foam treatment agent was foamed with dodecyl dimethyl benzyl ammonium chloride (cationic surfactant) by mechanical stirring, and adjusted with PVA (thickener) to obtain an aqueous foam treatment agent having a foaming ratio of 3.8 times and a viscosity of 750 cP. And (3) soaking the rubberized glove blanks obtained in the step (2) in the treating agent for 10 seconds, and then extracting. The rest of the conditions refer to example 1. The final glove product prepared has a surface with a micropore distribution density greater than that of example 1 and an average roughness about 1.34 times that of example 1.

Example 7

The coated glove with micropores on the surface of the glove is prepared according to the following steps:

(1) dipping the 13-needle polyester glove blank in a methanol solution of calcium chloride with the mass concentration of 2% for 1s, wherein the temperature of the glove blank is 45 ℃.

(2) Dipping the glove blank into a natural latex sizing material which is not foamed and has the viscosity of 2800cP, extracting, and drying in a 70 ℃ oven to 7 degrees to obtain the glove blank with the base rubber layer.

(3) Dipping the glove blank with the base rubber layer obtained in the step (2) into natural latex rubber with the foaming times of 1.2 times and the viscosity of 3500cP, and dripping and homogenizing the rubber after extracting to obtain the rubberized glove blank. The natural latex rubber material is prepared and foamed according to a conventional method.

(4) Preparing an aqueous foam treating agent, mechanically stirring and foaming by dodecyl dimethyl benzyl ammonium chloride (cationic surfactant), and adding PVA (thickening agent) for regulation to obtain the aqueous foam treating agent with the foaming times of 3.8 times and the viscosity of 550 cP. And (4) soaking the rubberized glove blanks obtained in the step (3) in the treating agent for 10 seconds, and then extracting.

(5) And (5) soaking the rubberized glove blanks treated in the step (4) in a 10% mass concentration acetic acid methanol solution for 8 seconds.

(6) And (4) drying the semi-finished product treated in the step (5) at 115 ℃ for 2h for vulcanization and drying to obtain the finished product of the natural rubber glove with a large number of micropore structures on the surface.

When the glove is observed under an electron microscope, the effect of the micropore structure is close to that shown in figure 1, but the abrasion resistance of the finished natural rubber glove prepared in the embodiment reaches 2500 revolutions, while the abrasion resistance of the finished natural rubber glove prepared in the embodiment 1 only has 2120 revolutions. The glove product made in this example was better than example 1 in terms of abrasion resistance, tear resistance, and cut resistance according to the EN388 standard test.

Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.