1. An antistatic radiation-proof ATO nano powder material is characterized by comprising the following important components: 100-110 parts of ATO powder, 10-16 parts of radiation-proof components, 12-18 parts of antistatic components, 14-20 parts of antioxidant and anticorrosive components, 3-6 parts of ultraviolet absorbers, 3-6 parts of wear-resistant resin fibers and 4-8 parts of wear-resistant resin fibers, wherein the radiation-proof components comprise methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate, the antistatic components comprise polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine, and the antioxidant and anticorrosive components comprise xylene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate and graphene.

2. The antistatic radiation-proof ATO nano-powder material as claimed in claim 1, is characterized by comprising the following important components: 108 parts of ATO powder 102, 12-14 parts of radiation-proof components, 14-16 parts of antistatic components, 16-18 parts of antioxidant and anticorrosive components, 4-5 parts of ultraviolet absorbers, 4-5 parts of wear-resistant resin fibers and 5-7 parts of wear-resistant resin fibers.

3. The antistatic radiation-proof ATO nano-powder material as claimed in claim 1, is characterized by comprising the following important components: 106 parts of ATO powder, 13 parts of radiation-proof component, 15 parts of antistatic component, 17 parts of antioxidant and anticorrosive component, 4.5 parts of ultraviolet absorber, 4.5 parts of wear-resistant resin fiber and 6 parts of wear-resistant resin fiber.

4. The ATO nano-powder material with antistatic property and radiation protection property as claimed in claim 1, wherein the ratio of methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butanol and lead methacrylate in the radiation protection component is 1:1:0.8:1.1: 1.

5. The ATO nano-powder material with antistatic property and radiation protection property as claimed in claim 1, wherein the ratio of polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine in the antistatic component is 1:0.9:0.8: 0.7.

6. The antistatic radiation-proof ATO nano-powder material as claimed in claim 1, wherein the ratio of xylene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate and graphene in said antioxidant and anticorrosive components is 1:1:1.2:0.8:0.9: 1.3.

7. The ATO nano powder material with antistatic property and radiation protection property as claimed in claim 1, wherein said radiation protection component preparation method comprises the following steps:

accurately weighing methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate;

adding the components into the aqueous solution, uniformly mixing, and mixing for 0.5-1 h at 70-80 ℃;

obtaining the radiation-proof component.

8. The ATO nano powder material with antistatic property and radiation protection property as claimed in claim 1, wherein the preparation method of the antistatic component comprises the following steps:

accurately weighing dimethyl siloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine;

adding the added components into the aqueous solution, heating and stirring to dissolve the components, slowly heating to 70-80 ℃, and uniformly mixing for 0.6-1.2 h;

an antistatic component is obtained.

9. The antistatic radiation-proof ATO nano powder material as claimed in claim 1, wherein said antioxidant and anticorrosive component preparation method comprises the following steps:

accurately weighing the components of dimethylbenzene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate and graphene;

adding the added components into the aqueous solution, heating and stirring to dissolve the components, slowly heating to 75-85 ℃, and uniformly mixing for 0.6-1.2 h;

obtaining the antioxidant and antiseptic component.

10. The antistatic radiation-proof ATO nano powder material according to claim 1, characterized in that the preparation method of said antistatic radiation-proof ATO nano powder material comprises the following steps:

adding ATO powder, a radiation-proof component, an antistatic component, an antioxidant and anticorrosive component, an ultraviolet absorbent, wear-resistant resin fibers and wear-resistant resin fibers into a reactor, and fully mixing;

slowly heating the reactor to 85-95 ℃, mixing for 2-3 h and curing;

and thirdly, grinding the obtained solidified material to obtain ATO nano powder.

Background

ATO is also called antimony-doped tin dioxide, mainly comprises tin oxide and antimony oxide, the grain diameter is mostly 5-80 nanometers, the nanometer ATO powder is blue or light blue powder, has the characteristics of high temperature resistance, corrosion resistance, good dispersibility and the like, has excellent optical and electrical properties, and is widely used in the fields of textiles, coatings, chemical fibers, polymer films and the like by utilizing the good electrical conductivity and optical properties of the nanometer ATO powder.

The existing ATO nano powder has poor performance and complex preparation, and can not meet the use requirement.

Disclosure of Invention

The invention aims to solve the defects that the existing ATO nano powder has poor performance, is complex to prepare and cannot meet the use requirement, and provides an antistatic radiation-proof ATO nano powder material.

In order to achieve the purpose, the invention adopts the following technical scheme:

an antistatic radiation-proof ATO nano powder material comprises the following important components: 100-110 parts of ATO powder, 10-16 parts of radiation-proof components, 12-18 parts of antistatic components, 14-20 parts of antioxidant and anticorrosive components, 3-6 parts of ultraviolet absorbers, 3-6 parts of wear-resistant resin fibers and 4-8 parts of wear-resistant resin fibers, wherein the radiation-proof components comprise methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate, the antistatic components comprise polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine, and the antioxidant and anticorrosive components comprise xylene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate and graphene.

Preferably, the radiation-proof paint comprises 108 parts of ATO powder 102, 12-14 parts of radiation-proof components, 14-16 parts of antistatic components, 16-18 parts of antioxidant and anticorrosive components, 4-5 parts of ultraviolet absorbers, 4-5 parts of wear-resistant resin fibers and 5-7 parts of wear-resistant resin fibers, wherein the radiation-proof components comprise methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate, the antistatic components comprise polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine, and the antioxidant and anticorrosive components comprise xylene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate and graphene.

Preferably, the radiation-proof paint comprises 106 parts of ATO powder, 13 parts of radiation-proof components, 15 parts of antistatic components, 17 parts of antioxidant and anticorrosive components, 4.5 parts of ultraviolet absorbers, 4.5 parts of wear-resistant resin fibers and 6 parts of wear-resistant resin fibers, wherein the radiation-proof components comprise methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate, the antistatic components comprise polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethylene imine, and the antioxidant and anticorrosive components comprise xylene, butyl acetate, titanium pigment, polypyrrole, sodium benzene sulfinate and graphene.

Preferably, the ratio of methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate in the radiation-proof component is 1:1:0.8:1.1: 1.

Preferably, the ratio of polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine in the antistatic component is 1:0.9:0.8: 0.7.

Preferably, the ratio of the dimethylbenzene to the butyl acetate to the titanium dioxide to the polypyrrole to the sodium benzene sulfinate to the graphene in the antioxidant and anticorrosive components is 1:1:1.2:0.8:0.9: 1.3.

Preferably, the preparation method of the radiation-proof component comprises the following steps:

firstly, accurately weighing methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate;

secondly, adding the components into the aqueous solution, uniformly mixing, and mixing for 0.5-1 h at 70-80 ℃;

thirdly, obtaining the radiation-proof component.

Preferably, the preparation method of the antistatic component comprises the following steps:

firstly, accurately weighing dimethyl siloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine;

secondly, adding the added components into the aqueous solution, heating and stirring the components to dissolve the components, slowly heating the mixture to 70-80 ℃, and uniformly mixing the components for 0.6-1.2 h;

thirdly, an antistatic component is obtained.

Preferably, the preparation method of the antioxidant preservative component comprises the following steps:

firstly, accurately weighing the components of dimethylbenzene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate and graphene;

secondly, adding the added components into the aqueous solution, heating and stirring the components to dissolve the components, slowly heating the mixture to 75-85 ℃, and uniformly mixing the components for 0.6-1.2 h;

thirdly, antioxidant and antiseptic components are obtained.

Preferably, the preparation method of the antistatic radiation-proof ATO nano powder material comprises the following steps:

firstly, adding ATO powder, a radiation-proof component, an antistatic component, an antioxidant and anticorrosive component, an ultraviolet absorbent, wear-resistant resin fibers and wear-resistant resin fibers into a reactor for fully mixing;

secondly, slowly heating the reactor to 85-95 ℃, mixing for 2-3 h and curing;

and thirdly, grinding the obtained solidified material to obtain ATO nano powder.

Compared with the prior art, the invention has the advantages that:

methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate in the radiation-proof components have good radiation-proof performance, and the radiation-proof performance of ATO nano powder is improved; the polydimethylsiloxane, the epoxidized polyamide resin, the polyvinyl alcohol and the polyethyleneimine in the set antistatic components have good antistatic performance, so that the antistatic performance of the ATO nano powder is improved; the xylene, butyl acetate, titanium pigment, polypyrrole, sodium benzene sulfinate and graphene in the arranged antioxidant and anticorrosive components have good antioxidant and anticorrosive properties, and the antioxidant and anticorrosive properties of the ATO nano powder are improved;

the ATO nano powder has the characteristics of high temperature resistance, corrosion resistance and good dispersibility, and improves the antistatic, radiation-proof, antioxidant and anticorrosive performances of the ATO nano powder.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.

Example one

An antistatic radiation-proof ATO nano powder material comprises the following important components: 100 parts of ATO powder, 10 parts of radiation-proof components, 12 parts of antistatic components, 14 parts of antioxidant and anticorrosive components, 3 parts of ultraviolet absorbers, 3 parts of wear-resistant resin fibers and 4 parts of wear-resistant resin fibers, wherein the radiation-proof components comprise methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate, the antistatic components comprise polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine, and the antioxidant and anticorrosive components comprise xylene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate and graphene.

In this example, the ratio of methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butanol, and lead methacrylate in the radiation-proof component was 1:1:0.8:1.1: 1.

In this example, the ratio of polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol, and polyethyleneimine in the antistatic component was 1:0.9:0.8: 0.7.

In this embodiment, the ratio of xylene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate, and graphene in the antioxidant and anticorrosive components is 1:1:1.2:0.8:0.9: 1.3.

In this embodiment, the preparation method of the radiation-proof component comprises the following steps:

firstly, accurately weighing methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate;

secondly, adding the components into the aqueous solution, uniformly mixing, and mixing for 0.5h at 70 ℃;

thirdly, obtaining the radiation-proof component.

In this example, the preparation of the antistatic component comprises the following steps:

firstly, accurately weighing dimethyl siloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine;

secondly, adding the added components into the aqueous solution, heating and stirring the components to dissolve the components, slowly heating the mixture to 70 ℃, and uniformly mixing the mixture for 0.6 hour;

thirdly, an antistatic component is obtained.

In this embodiment, the preparation method of the antioxidant preservative component comprises the following steps:

firstly, accurately weighing the components of dimethylbenzene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate and graphene;

secondly, adding the added components into the aqueous solution, heating and stirring the components to dissolve the components, slowly heating the mixture to 75 ℃, and uniformly mixing the components for 0.6 hour;

thirdly, antioxidant and antiseptic components are obtained.

In this embodiment, the preparation method of the antistatic radiation-proof ATO nano powder material includes the following steps:

firstly, adding ATO powder, a radiation-proof component, an antistatic component, an antioxidant and anticorrosive component, an ultraviolet absorbent, wear-resistant resin fibers and wear-resistant resin fibers into a reactor for fully mixing;

secondly, slowly heating the reactor to 85 ℃, mixing for 2 hours and curing;

and thirdly, grinding the obtained solidified material to obtain ATO nano powder.

Example two

An antistatic radiation-proof ATO nano powder material comprises the following important components: 106 parts of ATO powder, 13 parts of radiation-proof components, 15 parts of antistatic components, 17 parts of antioxidant and anticorrosive components, 4.5 parts of ultraviolet absorbers, 4.5 parts of wear-resistant resin fibers and 6 parts of wear-resistant resin fibers, wherein the radiation-proof components comprise methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate, the antistatic components comprise polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethylene imine, and the antioxidant and anticorrosive components comprise xylene, butyl acetate, titanium pigment, polypyrrole, sodium benzene sulfinate and graphene.

In this example, the ratio of methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butanol, and lead methacrylate in the radiation-proof component was 1:1:0.8:1.1: 1.

In this example, the ratio of polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol, and polyethyleneimine in the antistatic component was 1:0.9:0.8: 0.7.

In this embodiment, the ratio of xylene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate, and graphene in the antioxidant and anticorrosive components is 1:1:1.2:0.8:0.9: 1.3.

In this embodiment, the preparation method of the radiation-proof component comprises the following steps:

firstly, accurately weighing methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate;

secondly, adding the components into the aqueous solution, uniformly mixing, and mixing for 0.8h at 75 ℃;

thirdly, obtaining the radiation-proof component.

In this example, the preparation of the antistatic component comprises the following steps:

firstly, accurately weighing dimethyl siloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine;

secondly, adding the added components into the aqueous solution, heating and stirring the components to dissolve the components, slowly heating the mixture to 75 ℃, and uniformly mixing the mixture for 1 hour;

thirdly, an antistatic component is obtained.

In this embodiment, the preparation method of the antioxidant preservative component comprises the following steps:

firstly, accurately weighing the components of dimethylbenzene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate and graphene;

secondly, adding the added components into the aqueous solution, heating and stirring the components to dissolve the components, slowly heating the mixture to 80 ℃, and uniformly mixing the mixture for 1 hour;

thirdly, antioxidant and antiseptic components are obtained.

In this embodiment, the preparation method of the antistatic radiation-proof ATO nano powder material includes the following steps:

firstly, adding ATO powder, a radiation-proof component, an antistatic component, an antioxidant and anticorrosive component, an ultraviolet absorbent, wear-resistant resin fibers and wear-resistant resin fibers into a reactor for fully mixing;

secondly, slowly heating the reactor to 90 ℃, mixing for 2.5 hours and curing;

and thirdly, grinding the obtained solidified material to obtain ATO nano powder.

EXAMPLE III

An antistatic radiation-proof ATO nano powder material comprises the following important components: 110 parts of ATO powder, 16 parts of radiation-proof components, 18 parts of antistatic components, 20 parts of antioxidant and anticorrosive components, 6 parts of ultraviolet absorbers, 6 parts of wear-resistant resin fibers and 8 parts of wear-resistant resin fibers, wherein the radiation-proof components comprise methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate, the antistatic components comprise polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine, and the antioxidant and anticorrosive components comprise xylene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate and graphene.

In this embodiment, the ratio of methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol, and lead methacrylate in the radiation-proof component is 1:1:0.8:1.1: 1.

In this example, the ratio of polydimethylsiloxane, epoxidized polyamide resin, polyvinyl alcohol, and polyethyleneimine in the antistatic component was 1:0.9:0.8: 0.7.

In this embodiment, the ratio of xylene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate, and graphene in the antioxidant and anticorrosive components is 1:1:1.2:0.8:0.9: 1.3.

In this embodiment, the preparation method of the radiation-proof component comprises the following steps:

firstly, accurately weighing methyl methacrylate, dibenzoyl peroxide, dioctyl phthalate, n-butyl alcohol and lead methacrylate;

secondly, adding the components into the aqueous solution, uniformly mixing, and mixing for 1h at 80 ℃;

thirdly, obtaining the radiation-proof component.

In this example, the preparation of the antistatic component comprises the following steps:

firstly, accurately weighing dimethyl siloxane, epoxidized polyamide resin, polyvinyl alcohol and polyethyleneimine;

secondly, adding the added components into the aqueous solution, heating and stirring the components to dissolve the components, slowly heating the mixture to 80 ℃, and uniformly mixing the mixture for 1.2 hours;

thirdly, an antistatic component is obtained.

In this embodiment, the preparation method of the antioxidant preservative component comprises the following steps:

firstly, accurately weighing the components of dimethylbenzene, butyl acetate, titanium dioxide, polypyrrole, sodium benzene sulfinate and graphene;

secondly, adding the added components into the aqueous solution, heating and stirring the components to dissolve the components, slowly heating the mixture to 85 ℃, and uniformly mixing the mixture for 1.2 hours;

thirdly, antioxidant and antiseptic components are obtained.

In this embodiment, the preparation method of the antistatic radiation-proof ATO nano powder material includes the following steps:

firstly, adding ATO powder, a radiation-proof component, an antistatic component, an antioxidant and anticorrosive component, an ultraviolet absorbent, wear-resistant resin fibers and wear-resistant resin fibers into a reactor for fully mixing;

secondly, slowly heating the reactor to 95 ℃, mixing for 3 hours and curing;

and thirdly, grinding the obtained solidified material to obtain ATO nano powder.

Example four

In this embodiment, the detection of the radiation-proof, antistatic, antioxidant and anticorrosive properties of the obtained three ATO nano-powders specifically includes the following steps:

firstly, mixing three ATO nano powder materials according to the same proportion to obtain colloid with the same proportion;

secondly, coating the obtained colloid on a plastic plate or other plates in the same way;

thirdly, the three plates are placed under the conditions of the same radiation proportion, the same corrosivity and the same electrostatic particles for observation, the observation time is 10 hours, and the temperature and the humidity are under the same conditions;

fourthly, taking out the three plates to carry out radiation protection, antistatic, antioxidant and anticorrosive performance detection;

the following conclusions were reached;

a, detecting the three plates by using a radiation detector, wherein the higher the radiation proportion is, the poorer the radiation resistance is;

b, detecting the electrostatic particles on the surface of the plate by using an electrostatic particle detector, wherein the more the electrostatic particles are, the poorer the radiation resistance is;

c, detecting the corrosion degree of the plate, wherein the higher the corrosion degree of the plate is, the worse the corrosion resistance is;

the second embodiment is the best embodiment.

The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.