1. The utility model provides an electricity generate heat glass, includes cavity glass and sets up heating wire (2) in cavity glass, its characterized in that, cavity glass includes outer glass piece (3) and interior glass piece (4), and outer wall all bonds all around of outer glass piece (3) and interior glass piece (4) has outsourcing protection paster (1).

2. The electric heating glass according to claim 1, wherein the heating wires (2) are disposed on the outer wall of the top end of the inner glass sheet (4), and the heating wires (2) are distributed in the inner glass sheet (4) in a curved manner, and the heating wires (2) are distributed in a zigzag-shaped forming curved manner.

3. An electrically heating glass according to claim 1, characterised in that more than 85% of inert gas is filled between the outer glass sheet (3) and the inner glass sheet (4).

4. An electrically heating glass according to claim 3, wherein said inert gas is helium.

5. The electric heating glass according to claim 1, wherein a temperature sensor (5) is arranged on one side of the outer wall of the top of the inner glass sheet (4), a connector (6) is arranged on the outer wall of one side of the inner glass sheet (4), the connector (6) comprises a data connection port and a power connection port, the data connection port is connected with the signal output end of the temperature sensor (5), and the power connection port is connected with the electric heating wire (2).

6. An electric heating glass according to any one of claims 1-5, characterised in that the outer wall of the top of the outer glass sheet (3) is fixed with a number of display screens (7) by means of an adsorption mechanism.

7. The electric heating glass according to claim 6, wherein the adsorption mechanism comprises a soft adhesive tape (8) and an adhesive layer (9), the top end of the soft adhesive tape (8) is welded to the outer wall of the bottom end of the digital display screen (7), the bottom end of the soft adhesive tape (8) is of a groove-shaped structure, and the adhesive layer (9) is arranged on the bottom edge of the soft adhesive tape (8).

8. The manufacturing process flow of the electric heating glass according to claim 1, characterized by comprising the following steps:

s1: preparing zinc oxide graphene: dissolving 1-3g of graphite oxide in 10-40ul of ethylene glycol, performing ultrasonic treatment for 20-40min to obtain a graphene oxide solution, adding 1g of zinc dioxyacetate into the ethylene glycol, stirring for 5-8min to dissolve the zinc dioxyacetate, then adding the graphene oxide solution, uniformly stirring, then adjusting the pH =9, stirring for 30min, adding 10-40ul of hydrazine hydrate to reduce the graphene oxide, and then putting the obtained mixed solution into a reactor with the temperature of 100-200-^oC. Stirring and reacting for 10-18h in a reaction kettle at the rotating speed of 500 revolutions per minute, and centrifugally filtering and drying to obtain zinc oxide graphene;

s2: outer glass pretreatment: taking toughened glass as an outer glass sheet (3), cutting the outer glass sheet (3) into a proper size, removing burrs and uneven surfaces on the surface, washing and cleaning the outer glass sheet by deionized water, drying the outer glass sheet, and then coating a layer of transparent titanium dioxide photocatalyst film on the surface of the outer glass sheet (3);

s3: surface treatment of inner glass: using colorless float glass as a substrate of the inner glass sheet (4), cutting the inner glass sheet (4) to have the same size as the outer glass sheet (3), cleaning and drying the inner glass sheet (4) by using deionized water, and preheating the inner glass sheet (4) to 40-60 DEG^oC, adding the zinc oxide graphene obtained in the step S1 into ethylene glycol, uniformly mixing, and spin-coating the solution on a spin coater to enable the inner glass sheet (4) to be attached with a film;

s4: printing an electrode: printing an electric heating wire on one surface of the coating film of the inner glass sheet (4), and installing a temperature sensor;

s5: blanking of the aluminum parting strips: cutting the aluminum adhesive tape to be matched with the specifications of the outer glass sheet (3) and the inner glass sheet (4), and removing burrs and oil stains on the surface;

s6: assembling the aluminum parting strips: the processed aluminum parting strip frame is coated with butyl rubber, and a butyl rubber coating machine can ensure that the rubber is uniformly discharged, does not leak or break and is uniformly coated on the aluminum strip to ensure the sealing effect; the spacer bar molecular sieve filling holes and the angle plug-in are connected with the plug-in and must be completely filled with butyl rubber; the aluminum frame coated with the butyl rubber is hung on an aluminum frame turnover frame to wait for mixing, so that oil stain and dust pollution is avoided; the isolation frame filled with the molecular sieve is synthesized to be hollow within 30-50 min;

s7: glass sheet combination: rolling the laminated glass by using a roller press, adjusting the opening and closing thickness of the roller press to be 2-3 mm less than the nominal thickness of the glass, and setting the pressure of a roller to be 0.6 Mpa;

s8, filling argon gas with a concentration of more than 85% into the hollow layer, and then attaching the outer protective patch (1), packaging and sealing.

9. The manufacturing process of an electrothermal glass according to claim 8, wherein the deionization cleaning process in steps S2 and S3 is performed by machine cleaning, and before cleaning, the glass should be inspected to be free of scratches.

10. The manufacturing process of an electrothermal glass according to claim 8 or 9, wherein the drying air used in the steps S2 and S3 is filtered, and after cleaning and drying, the electrothermal glass is sorted by wearing oil-free white gloves and detected by illumination to ensure no water stain, water drop or other stains.

Background

At present, when the outdoor glass is used in cold winter, particularly in northern areas, a layer of frost is often hung on the outdoor glass, so that the sight of people is blocked, and if the outdoor glass is frosted on the glass of shops, hotels, show windows, traffic posts and the like, the normal business and life of people are influenced.

Through retrieval, the patent with Chinese patent application number 201910211148.2 discloses defogging glass and a manufacturing method thereof, wherein the defogging glass comprises a glass body, a groove is arranged on one surface of the glass body, a metal circuit is arranged on the groove, and a positive terminal and a negative terminal are respectively arranged at two ends of the metal circuit;

processing a groove on one surface of the glass body by using a laser processing mode; cleaning foreign matters generated on the glass body by laser processing; and plating a metal circuit on the groove of the glass body by using a chemical plating mode.

The defogging glass in the patent has the following defects: the external protection effect in the glass is poor, and the simple preparation process causes the use function of the glass to be insufficient and the self-cleaning performance to be lacked.

Disclosure of Invention

The invention aims to solve the defects in the prior art and provides electric heating glass and a manufacturing process flow thereof.

In order to achieve the purpose, the invention adopts the following technical scheme:

the utility model provides an electricity glass that generates heat, includes cavity glass and sets up the heating wire in cavity glass, cavity glass includes outer glass piece and interior glass piece, and outer wall all bonds all around of outer glass piece and interior glass piece has outsourcing protection paster.

Preferably: the heating wires are arranged on the outer wall of the top end of the inner glass sheet, are distributed in the inner glass sheet in a curve shape, and are distributed in a curve shape formed by zigzag.

Preferably: and more than% of inert gas is filled between the outer glass sheet and the inner glass sheet.

Preferably: the inert gas is helium.

Preferably: one side of interior glass piece top outer wall is provided with temperature sensor, and interior glass piece one side outer wall is provided with the connector, and the connector includes data connection port and power connection port, and data connection port connects temperature sensor's signal output part, and power connection port is connected with the heating wire.

Preferably: the top outer wall of outer glass piece is fixed with the digital display screen through adsorption apparatus structure.

Preferably: adsorption equipment constructs including soft adhesive tape and adhesive linkage, and the top of soft adhesive tape fuses in the bottom outer wall of digital display screen, and the bottom of soft adhesive tape is fluted type structure, and the adhesive linkage sets up in the base of soft adhesive tape.

A manufacturing process flow of electric heating glass comprises the following steps:

s1: preparing zinc oxide graphene: dissolving 1-3g of graphite oxide in 10-40ul of ethylene glycol, performing ultrasonic treatment for 20-40min to obtain a graphene oxide solution, adding 1g of zinc dioxyacetate into the ethylene glycol, stirring for 5-8min to dissolve the zinc dioxyacetate, then adding the graphene oxide solution, uniformly stirring, then adjusting the pH =9, stirring for 30min, adding 10-40ul of hydrazine hydrate to reduce the graphene oxide, and then putting the obtained mixed solution into a reactor with the temperature of 100-200-^oC. Stirring and reacting for 10-18h in a reaction kettle at the rotating speed of 500 revolutions per minute, and centrifugally filtering and drying to obtain zinc oxide graphene;

s2: outer glass pretreatment: cutting toughened glass serving as an outer glass sheet into a proper size, removing burrs and uneven surfaces on the surface, washing and cleaning the outer glass sheet by deionized water, drying the outer glass sheet, and coating a layer of transparent titanium dioxide photocatalyst film on the surface of the outer glass sheet;

s3: surface treatment of inner glass: cutting the inner glass sheet into the same size as the outer glass sheet, washing with deionized water, drying, and preheating the inner glass sheet to 40-60 deg.C^oC, adding the zinc oxide graphene obtained in the step S1 into ethylene glycol, uniformly mixing, and spin-coating the solution on a spin coater to enable the inner glass sheet to be attached with a film;

s4: printing an electrode: printing an electric heating wire on one surface of the inner glass sheet coated with the film, and mounting a temperature sensor;

s5: blanking of the aluminum parting strips: cutting the aluminum adhesive tape to be matched with the specifications of the outer glass sheet and the inner glass sheet, and removing burrs and oil stains on the surface;

s6: assembling the aluminum parting strips: the processed aluminum parting strip frame is coated with butyl rubber, and a butyl rubber coating machine can ensure that the rubber is uniformly discharged, does not leak or break and is uniformly coated on the aluminum strip to ensure the sealing effect; the spacer bar molecular sieve filling holes and the angle plug-in are connected with the plug-in and must be completely filled with butyl rubber; the aluminum frame coated with the butyl rubber is hung on an aluminum frame turnover frame to wait for mixing, so that oil stain and dust pollution is avoided; the isolation frame filled with the molecular sieve is synthesized to be hollow within 30-50 min;

s7: glass sheet combination: rolling the laminated glass by using a roller press, adjusting the opening and closing thickness of the roller press to be 2-3 mm less than the nominal thickness of the glass, and setting the pressure of a roller to be 0.6 Mpa;

s8, filling argon gas above 85% into the hollow layer, and then attaching the outer protective patch, packaging and sealing.

Preferably: the deionization cleaning process in the steps S2 and S3 adopts a machine cleaning method for cleaning, and before cleaning, the glass is checked to be free from scratches.

Preferably: and the drying air used in the drying in the steps S2 and S3 needs to be filtered, and after the drying and cleaning, oil-free and clean white gloves need to be worn for sorting, and illumination detection is used for ensuring no water stains, water beads and other stains.

The invention has the beneficial effects that:

1. the arrangement of the outer protective paster can achieve a certain protective effect on the periphery of the hollow glass, so that the abrasion of the outer edge is reduced, and the risk of transportation damage is reduced; the heating wire is zigzag and forms curved distribution, and can increase the length of heating wire and ensure the homogeneity of heating wire heating simultaneously when not influencing the glass light transmissivity, avoids the local too high or local too low phenomenon of electric heating temperature to take place in the glass.

2. Coating a layer of transparent titanium dioxide photocatalyst film on the surface of the outer glass sheet; when the light is irradiated by sunlight, fluorescent lamp, ultraviolet ray, etc. and in the condition of being excited by external light, the organic matter and pollutant attached to the surface are changed into carbon dioxide and water and automatically eliminated, so as to reach the self-cleaning effect.

3. Attaching a zinc oxide graphene film on the inner glass sheet; the light transmittance and the electric conductivity of the inner glass sheet can be greatly improved; the inert gas argon is filled in the hollow position, so that the cost is low, the thermal resistance value of the hollow glass can be increased, the frost prevention effect can be more remarkable, and the heating wire can be effectively prevented from being oxidized.

Drawings

FIG. 1 is a schematic view of an electric heating glass according to example 1;

FIG. 2 is an enlarged view of a portion of the heating wire of the electric heating glass in accordance with example 1;

FIG. 3 is a schematic view of the structure of an electrothermal glass according to example 2;

fig. 4 is a schematic structural view of a digital display screen in an electric heating glass as provided in example 2;

fig. 5 is a flow chart of a process for manufacturing an electrothermal glass according to the present invention.

In the figure: the glass plate comprises an outer wrapping protection patch 1, an electric heating wire 2, an outer glass plate 3, an inner glass plate 4, a temperature sensor 5, a connector 6, a digital display screen 7, a soft adhesive tape 8 and a bonding layer 9.

Detailed Description

The technical solution of the present patent will be described in further detail with reference to the following embodiments.

In the description of this patent, it is to be understood that the terms "center," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like are used in the orientations and positional relationships indicated in the drawings for the convenience of describing the patent and for the simplicity of description, and are not intended to indicate or imply that the referenced devices or elements must have a particular orientation, be constructed and operated in a particular orientation, and are not to be considered limiting of the patent.

In the description of this patent, it is noted that unless otherwise specifically stated or limited, the terms "mounted," "connected," and "disposed" are to be construed broadly and can include, for example, fixedly connected, disposed, detachably connected, disposed, or integrally connected and disposed. The specific meaning of the above terms in this patent may be understood by those of ordinary skill in the art as appropriate.

Example 1:

an electric heating glass is shown in fig. 1, fig. 2 and fig. 5, and comprises hollow glass and an electric heating wire 2 arranged in the hollow glass, wherein the hollow glass comprises an outer glass sheet 3 and an inner glass sheet 4, outer-coating protective patches 1 are bonded around the outer walls of the outer glass sheet 3 and the inner glass sheet 4, and the arrangement of the outer-coating protective patches 1 can achieve a certain protection effect around the hollow glass, so that the abrasion of the outer edge is reduced, and the risk of transportation damage is reduced;

the heating wires 2 are arranged on the outer wall of the top end of the inner glass sheet 4, the heating wires 2 are distributed in the inner glass sheet 4 in a curved manner, and the heating wires 2 are distributed in a zigzag manner to form a curved manner, so that the light transmittance of the glass is not influenced, the length of the heating wires 2 is increased, the heating uniformity of the heating wires is guaranteed, and the phenomenon that the electric heating temperature in the glass is locally too high or the local temperature is too low is avoided;

more than 85% of inert gas is filled between the outer glass sheet 3 and the inner glass sheet 4, the components of the inert gas are not limited, and in the embodiment, the preferred inert gas is helium, so that the production cost is reduced by easily obtaining the helium;

wherein, one side of 4 top outer walls of interior glass pieces is provided with temperature sensor 5, and 4 one side outer walls of interior glass pieces are provided with connector 6, and connector 6 includes data connection port and power connection port, and data connection port connects temperature sensor 5's signal output part, and power connection port connects heating wire 2 to external power supply and data terminal.

A manufacturing process of electric heating glass comprises the following steps:

s1: preparing zinc oxide graphene: dissolving graphite oxide in ethylene glycol, performing ultrasonic treatment for 20-40min to obtain a graphene oxide solution, adding 1g of zinc dioxyacetate into the ethylene glycol, stirring for 5-8min to dissolve the zinc dioxyacetate, then adding the graphene oxide solution, uniformly stirring, then adjusting the pH =9, stirring for 30min, adding 10-40ul of hydrazine hydrate to reduce the graphene oxide, and then putting the obtained mixed solution into a reactor at the temperature of 100-200-^oC. In a reaction kettle with the rotating speed of 500 revolutions per minuteStirring for reaction for 10-18h, and centrifugally filtering and drying to obtain zinc oxide graphene;

s2: outer glass pretreatment: taking toughened glass as an outer glass sheet 3, cutting the outer glass sheet 3 into a proper size, removing burrs and uneven surfaces on the surface, washing and cleaning the outer glass sheet by deionized water, drying the outer glass sheet, and then coating a layer of transparent titanium dioxide photocatalyst film on the surface of the outer glass sheet 3; when the light is irradiated by sunlight, fluorescent lamp, ultraviolet ray, etc. and in the condition of being excited by external light, the organic matter and pollutant attached to the surface are changed into carbon dioxide and water and automatically eliminated, so as to reach the self-cleaning effect.

S3: surface treatment of inner glass: using colorless float glass as the substrate of the inner glass sheet 4, cutting the inner glass sheet 4 to the same size as the outer glass sheet 3, cleaning with deionized water, drying, and preheating the inner glass sheet 4 to 40-60%^oC, adding the zinc oxide graphene obtained in the step S1 into ethylene glycol, uniformly mixing, and spin-coating the solution on a spin coater to enable the inner glass sheet 4 to be attached with a film; the light transmittance and the electric conductivity of the inner glass sheet can be greatly improved.

S4: printing an electrode: printing an electric heating wire on one surface of the inner glass sheet 4 coated with the film, and installing a temperature sensor;

s5: blanking of the aluminum parting strips: cutting the aluminum adhesive tape to the specification which is matched with the outer glass sheet 3 and the inner glass sheet 4, and removing burrs and oil stains on the surface;

s6: assembling the aluminum parting strips: the processed aluminum parting strip frame is coated with butyl rubber, and a butyl rubber coating machine can ensure that the rubber is uniformly discharged, does not leak or break and is uniformly coated on the aluminum strip to ensure the sealing effect; the spacer bar molecular sieve filling holes and the angle plug-in are connected with the plug-in and must be completely filled with butyl rubber; the aluminum frame coated with the butyl rubber is hung on an aluminum frame turnover frame to wait for mixing, so that oil stain and dust pollution is avoided; the isolation frame filled with the molecular sieve is synthesized to be hollow within 30-50 min;

s7: glass sheet combination: rolling the laminated glass by using a roller press, adjusting the opening and closing thickness of the roller press to be 2-3 mm less than the nominal thickness of the glass, and setting the pressure of a roller to be 0.6 Mpa;

s8, filling argon gas with a concentration of more than 85% into the hollow layer, and then attaching the outer protective patch 1, packaging and sealing.

In the steps S2 and S3, the deionization cleaning process is cleaned by a machine cleaning method, glass is inspected to be free of scratches before cleaning, drying air used in drying needs to be filtered, white gloves which are oil-free and clean need to be worn for sorting after cleaning and drying, and other stains such as water stains and water drops are ensured to be free of through illumination detection; so as to ensure the adhesion and cleanliness of the sealant and the glass.

Example 2:

an electric heating glass, as shown in fig. 3 and 4, for the convenience of knowing the temperature of the glass; the present embodiment is modified from embodiment 1 as follows: a plurality of display screens 7 are fixed on the outer wall of the top of the outer glass sheet 3 through an adsorption mechanism;

wherein, adsorption equipment includes soft adhesive tape 8 and adhesive linkage 9, and the top of soft adhesive tape 8 is welded and is connected in the bottom outer wall of digital display screen 7, and the bottom of soft adhesive tape 8 is fluted type structure, and adhesive linkage 9 sets up in the base of soft adhesive tape 8, and the fluted type structure of soft adhesive tape 8 below can turn into sucking disc formula structure with soft adhesive tape 8, and adhesive linkage 9 of arranging simultaneously can effectively promote the adsorption affinity of digital display screen 7 on outer glass piece 3, avoids digital display screen 7 to drop, and temperature sensor 5 can be connected to digital display screen 7, learns glass's temperature in real time.

In use, the adhesive layer 9 is slowly adhered to the outer glass sheet 3 from one side, and air in the groove is slowly exhausted to form a suction cup, so that the digital display 7 is stably adhered to the outer glass sheet 3.

The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.