1. The special preservative treatment process for the branch artware is characterized by comprising the following steps of:

(1) preparation of the treating agent:

A. weighing 4-5 parts of nisin, 1-2 parts of natamycin, 0.7-0.9 part of lysozyme, 5-7 parts of carnauba wax, 3-4 parts of palmitic acid, 3.2-3.6 parts of glycerol monocaprylate, 2.4-3 parts of sodium sulfite, 4-8 parts of D-mannitol, 2-4 parts of calcium silicate, 2.3-2.7 parts of propylene glycol alginate and 90-100 parts of pure water in corresponding parts by weight for later use;

B. placing the carnauba wax, the palmitic acid, the glyceryl monocaprylate, the sodium sulfite, the D-mannitol, the calcium silicate, the propylene glycol alginate and the pure water which are weighed in the operation A into a homogenizer for homogenization treatment, and obtaining a mixture for later use after the homogenization treatment;

C. placing the mixture obtained in the operation A and the mixture obtained in the operation B into a stirring tank, and carrying out variable speed stirring treatment;

(2) surface activation treatment:

placing the branch artware to be treated in an ultraviolet environment for ultraviolet irradiation treatment, performing ultrasonic treatment while performing ultraviolet irradiation, and taking out for later use;

(3) coating treatment:

uniformly coating the treating agent obtained in the step (1) on the surface of the branch artware subjected to surface activation treatment in the step (2);

(4) and (3) constant-temperature drying treatment:

and (4) placing the branch artware coated in the step (3) into a constant-temperature drying box for drying treatment.

2. The special anti-corrosion treatment process for the branch artware as claimed in claim 1, wherein the working pressure of the homogenizer in the homogenizing treatment in the operation B in the step (1) is controlled to be 110-120 MPa, and the time is 8-10L/h.

3. The special anti-corrosion treatment process for the branch artware as claimed in claim 1, wherein the variable speed stirring treatment in the operation C in the step (1) is carried out by stirring at 400-600 rpm for 20-30 min, then stirring at 2000-3000 rpm for 8-12 min, and then stirring at 500-700 rpm for 30-40 min.

4. The special anticorrosion treatment process for the branch artware according to claim 1, wherein the distance from the highest point of the branch artware to the ultraviolet lamp during the ultraviolet irradiation treatment in the step (2) is 2-4 cm, the frequency of the ultrasonic wave during the ultrasonic treatment is controlled to be 30-50 kHz, and the treatment time is 40-50 min.

5. The special preservative treatment process for the branch artware according to claim 1, wherein the drying temperature is controlled to be 55-65 ℃ during the constant-temperature drying treatment in the step (4).

Background

The branch handicraft is a wood product, is a biological material, contains rich cellulose, is a complex polysaccharide, provides nutrients for wood decay fungi and mould fungi under certain temperature and humidity environment, and is extremely easy to be damaged by fungi and ants, thereby changing the appearance and reducing the strength. The existing method for improving the corrosion resistance of the preservative is mainly to spray the preservative on the surface of the preservative, and the preservative is mostly a chemical reagent, not only has pungent smell, but also causes certain environmental pollution. In addition, if the preservative is directly sprayed on the surface of the branch artware, the preservative effect is only temporary and is not obvious. Therefore, the development and research of a special anticorrosion treatment process for the branch artware with durable anticorrosion property are urgently needed.

Nisin: produced by the prokaryote streptococcus lactis which stimulates metabolism, belongs to one of bacteriocins, has wide antibacterial spectrum, and is a biodegradable non-toxic natural preservative. Early studies show that the compound can effectively inhibit the growth and the propagation of most gram-positive bacteria of food spoilage, clostridium botulinum, staphylococcus aureus, streptococcus hemolyticus, heat-resistant spoilage bacteria and other microorganisms. The antibacterial principle is as follows: after the addition of the "adsorption binding partner" by nonspecific (positive and negative charge effects) on the cell membrane of gram-negative bacteria microorganisms, the membrane structure is invaded and destroyed to form a multi-permeable pore channel, the intracellular osmotic pressure is changed, and the cells are inactivated by autolysis.

Natamycin: is a microbial food preservative separated from streptomyces nattararii, streptomyces chattanoagatus, streptomyces fuscopsis and the like in actinomycetes after biological fermentation. Can inhibit fungi, yeasts, certain protozoa and certain algae, but has no inhibition effect on bacteria and viruses, the natamycin is non-toxic and has good chemical stability, is insoluble in water and grease, most of the natamycin taken into a human body can be discharged along with excrement, and cannot be enriched in the human body. The principle of gas mould proofing is as follows: natamycin (lactone ring structure) can react with sterol compounds on fungal cell membranes, thereby triggering structural changes of the cell membrane to rupture, leading to leakage of cell contents and eventual death by inactivation, but natamycin cannot inhibit the growth of putrefying bacteria.

Lysozyme: is a hydrolase composed of polypeptide chains and acts exclusively on the cell wall of microorganisms. Lysozyme has inhibitory effects on gram-positive bacteria, fungi and viruses, but has little effect on gram-negative bacteria. The bacteriostatic principle is as follows: lysozyme can hydrolyze and break beta-1, 4 glycosidic bonds formed between N-acetylmuramic acid on peptidoglycan of cell wall and N-acetylglucosamine acetate through active centers in the spatial structure of protein, so that cell wall is damaged, cell contents leak out, and finally cell autolysis death is caused.

The microbial preservative has natural and non-toxic characteristics, and can not cause environmental pollution when being used for preserving the branch artware, but has a single bacteriostatic range and needs to be used together with other preservatives.

Disclosure of Invention

The invention aims to provide a special anti-corrosion treatment process for branch artware aiming at the existing problems.

The invention is realized by the following technical scheme:

a special anti-corrosion treatment process for branch artware comprises the following steps:

(1) preparation of the treating agent:

A. weighing 4-5 parts of nisin, 1-2 parts of natamycin, 0.7-0.9 part of lysozyme, 5-7 parts of carnauba wax, 3-4 parts of palmitic acid, 3.2-3.6 parts of glycerol monocaprylate, 2.4-3 parts of sodium sulfite, 4-8 parts of D-mannitol, 2-4 parts of calcium silicate, 2.3-2.7 parts of propylene glycol alginate and 90-100 parts of pure water in corresponding parts by weight for later use;

B. placing the carnauba wax, the palmitic acid, the glyceryl monocaprylate, the sodium sulfite, the D-mannitol, the calcium silicate, the propylene glycol alginate and the pure water which are weighed in the operation A into a homogenizer for homogenization treatment, and obtaining a mixture for later use after the homogenization treatment;

C. placing the mixture obtained in the operation A and the mixture obtained in the operation B into a stirring tank, and carrying out variable speed stirring treatment;

(2) surface activation treatment:

placing the branch artware to be treated in an ultraviolet environment for ultraviolet irradiation treatment, performing ultrasonic treatment while performing ultraviolet irradiation, and taking out for later use;

(3) coating treatment:

uniformly coating the treating agent obtained in the step (1) on the surface of the branch artware subjected to surface activation treatment in the step (2);

(4) and (3) constant-temperature drying treatment:

and (4) placing the branch artware coated in the step (3) into a constant-temperature drying box for drying treatment.

Further, the working pressure of the homogenizer is controlled to be 110-120 MPa and the time is 8-10L/h during the homogenization treatment in the operation B of the step (1).

Further, the variable speed stirring treatment in the operation C in the step (1) is firstly stirring at 400-600 rpm for 20-30 min, then stirring at 2000-3000 rpm for 8-12 min, and then stirring at 500-700 rpm for 30-40 min.

Further, the distance between the highest point of the branch handicraft and the ultraviolet lamp during the ultraviolet irradiation treatment in the step (2) is 2-4 cm, the frequency of ultrasonic waves during the ultrasonic treatment is controlled to be 30-50 kHz, and the treatment time is 40-50 min.

Further, the drying temperature is controlled to be 55-65 ℃ during the constant-temperature drying treatment in the step (4).

By adopting the technical scheme, carnauba wax, palmitic acid, glyceryl monocaprylate, sodium sulfite, D-mannitol, calcium silicate, propylene glycol alginate and pure water are jointly placed in a homogenizer for homogenization treatment according to a proper weight ratio, the selected materials are food-grade components, all the raw materials are contacted with each other in the homogenizer, the raw materials collide at a high speed along with the homogenization process to finally form a homogenized mixture, the mixture is uniformly stirred with nisin, natamycin and lysozyme, the three microbial components are immersed in the mixture and mutually fused with the mixture, when the mixture is sprayed on the surface of a branch handicraft, the branch handicraft is originally a biological material, so the treating agent prepared by the method can quickly and effectively act on the branch handicraft, the three microbial components have mutual synergistic effect, so that the problem of single antiseptic effect of the microbial components in a unit is effectively solved. This application carries out surface activation before spraying and covers, the main objective is in order to improve the surface activity of branch handicraft, thereby strengthen the adhesive adhesion nature of treating agent, the concrete branch handicraft of placing in the ultraviolet environment carries out the ultraviolet irradiation processing, carry out the auxiliary action of ultrasonic wave simultaneously, both cooperate each other, make the surface of branch handicraft produce a large amount of free radicals, further addition specific functional group, improve the surface properties of branch handicraft, promote the adhesion of treating agent, this processing still goes out to destroy partial ray cell simultaneously, the transmission path of moisture has been enlarged, in the drying process, accelerate the loss of moisture, can prevent that high temperature drying from causing the harm to the handicraft, can also the dry effect of efficient play.

Compared with the prior art, the invention has the following advantages:

the application provides a special anti-corrosion treatment process for branch artware, which is characterized in that after the surface of the branch artware is subjected to surface activation treatment, a specially-made treatment agent is uniformly coated on the surface of the branch artware subjected to surface activation treatment, and nisin, natamycin and lysozyme in the treatment agent act on the branch artware under the mutual synergistic action, so that the branch artware has broad-spectrum antibacterial property and remarkable anti-corrosion property, and the anti-corrosion property is lasting and effective.

Detailed Description

A special anti-corrosion treatment process for branch artware comprises the following steps:

(1) preparation of the treating agent:

A. weighing 4-5 parts of nisin, 1-2 parts of natamycin, 0.7-0.9 part of lysozyme, 5-7 parts of carnauba wax, 3-4 parts of palmitic acid, 3.2-3.6 parts of glycerol monocaprylate, 2.4-3 parts of sodium sulfite, 4-8 parts of D-mannitol, 2-4 parts of calcium silicate, 2.3-2.7 parts of propylene glycol alginate and 90-100 parts of pure water in corresponding parts by weight for later use;

B. placing the carnauba wax, the palmitic acid, the glyceryl monocaprylate, the sodium sulfite, the D-mannitol, the calcium silicate, the propylene glycol alginate and the pure water weighed in the operation A into a homogenizer together for homogenization treatment, controlling the working pressure of the homogenizer to be 110-120 MPa and the time to be 8-10L/h, and obtaining a mixture for later use after completion;

C. placing the mixture obtained in the operation A and the mixture obtained in the operation B into a stirring tank, and carrying out variable speed stirring treatment, wherein the mixture is stirred at 400-600 rpm for 20-30 min, then stirred at 2000-3000 rpm for 8-12 min, and then stirred at 500-700 rpm for 30-40 min;

(2) surface activation treatment:

placing the branch artware to be treated in an ultraviolet environment for ultraviolet irradiation treatment, wherein the distance between the highest point of the branch artware and an ultraviolet lamp is 2-4 cm, carrying out ultrasonic treatment while irradiating the branch artware by ultraviolet light, controlling the frequency of the ultrasonic wave to be 30-50 kHz, and taking out the branch artware for later use after the branch artware is treated for 40-50 min;

(3) coating treatment:

uniformly coating the treating agent obtained in the step (1) on the surface of the branch artware subjected to surface activation treatment in the step (2);

(4) and (3) constant-temperature drying treatment:

and (4) drying the branch artware coated in the step (3) at 55-65 ℃ in a constant-temperature drying box.

For further explanation of the present invention, reference will now be made to the following specific examples.

Example 1

A special anti-corrosion treatment process for branch artware comprises the following steps:

(1) preparation of the treating agent:

A. weighing 4 parts of nisin, 1 part of natamycin, 0.7 part of lysozyme, 5 parts of carnauba wax, 3 parts of palmitic acid, 3.2 parts of glycerol monocaprylate, 2.4 parts of sodium sulfite, 4 parts of D-mannitol, 2 parts of calcium silicate, 2.3 parts of propylene glycol alginate and 90 parts of pure water in corresponding parts by weight for later use;

B. placing the carnauba wax, the palmitic acid, the glyceryl monocaprylate, the sodium sulfite, the D-mannitol, the calcium silicate, the propylene glycol alginate and the pure water which are weighed in the operation A into a homogenizer together for homogenization treatment, controlling the working pressure of the homogenizer to be 110MPa and the time to be 8L/h, and obtaining a mixture for later use after completion;

C. placing the mixture obtained in the operation A, the nisin, the natamycin, the lysozyme and the operation B into a stirring tank, and carrying out variable speed stirring treatment, wherein the mixture is stirred at 400rpm for 20min, then at 2000rpm for 8min, and then at 500rpm for 30 min;

(2) surface activation treatment:

placing the branch artware to be treated in an ultraviolet environment for ultraviolet irradiation treatment, wherein the distance between the highest point of the branch artware and an ultraviolet lamp is 2cm, carrying out ultrasonic treatment while irradiating the branch artware by ultraviolet light, controlling the frequency of the ultrasonic wave to be 30kHz, and taking out the branch artware for later use after 40min of treatment;

(3) coating treatment:

uniformly coating the treating agent obtained in the step (1) on the surface of the branch artware subjected to surface activation treatment in the step (2);

(4) and (3) constant-temperature drying treatment:

and (4) drying the branch artware coated in the step (3) at 55 ℃ in a constant-temperature drying box.

Example 2

A special anti-corrosion treatment process for branch artware comprises the following steps:

(1) preparation of the treating agent:

A. weighing 4.5 parts of nisin, 1.6 parts of natamycin, 0.8 part of lysozyme, 6 parts of carnauba wax, 3.5 parts of palmitic acid, 3.4 parts of glycerol monocaprylate, 2.7 parts of sodium sulfite, 6 parts of D-mannitol, 3 parts of calcium silicate, 2.5 parts of propylene glycol alginate and 95 parts of pure water in corresponding parts by weight for later use;

B. placing the carnauba wax, the palmitic acid, the glyceryl monocaprylate, the sodium sulfite, the D-mannitol, the calcium silicate, the propylene glycol alginate and the pure water which are weighed in the operation A into a homogenizer together for homogenization treatment, controlling the working pressure of the homogenizer to be 115MPa and the time to be 9L/h, and obtaining a mixture for later use after completion;

C. placing the mixture obtained in the operation A, the nisin, the natamycin, the lysozyme and the operation B in a stirring tank, and carrying out variable speed stirring treatment, wherein the mixture is stirred at 500rpm for 25min, then at 2500rpm for 10min, and then at 600rpm for 35 min;

(2) surface activation treatment:

placing the branch artware to be treated in an ultraviolet environment for ultraviolet irradiation treatment, wherein the distance between the highest point of the branch artware and an ultraviolet lamp is 3cm, carrying out ultrasonic treatment while irradiating the branch artware by ultraviolet light, controlling the frequency of the ultrasonic wave to be 40kHz, and taking out the branch artware for later use after 45min of treatment;

(3) coating treatment:

uniformly coating the treating agent obtained in the step (1) on the surface of the branch artware subjected to surface activation treatment in the step (2);

(4) and (3) constant-temperature drying treatment:

and (4) drying the branch artware coated in the step (3) in a constant-temperature drying box at 60 ℃.

Example 3

A special anti-corrosion treatment process for branch artware comprises the following steps:

(1) preparation of the treating agent:

A. weighing 5 parts of nisin, 2 parts of natamycin, 0.9 part of lysozyme, 7 parts of carnauba wax, 4 parts of palmitic acid, 3.6 parts of glycerol monocaprylate, 3 parts of sodium sulfite, 8 parts of D-mannitol, 4 parts of calcium silicate, 2.7 parts of propylene glycol alginate and 100 parts of pure water in corresponding parts by weight for later use;

B. placing the carnauba wax, the palmitic acid, the glyceryl monocaprylate, the sodium sulfite, the D-mannitol, the calcium silicate, the propylene glycol alginate and the pure water which are weighed in the operation A into a homogenizer together for homogenization treatment, controlling the working pressure of the homogenizer to be 120MPa and the time to be 10L/h, and obtaining a mixture for later use after completion;

C. placing the mixture obtained in the operation A, the nisin, the natamycin, the lysozyme and the operation B in a stirring tank, and carrying out variable speed stirring treatment, wherein the mixture is stirred at 600rpm for 30min, then at 3000rpm for 12min, and then at 700rpm for 40 min;

(2) surface activation treatment:

placing the branch artware to be treated in an ultraviolet environment for ultraviolet irradiation treatment, wherein the distance between the highest point of the branch artware and an ultraviolet lamp is 4cm, carrying out ultrasonic treatment while irradiating the branch artware by ultraviolet light, controlling the frequency of the ultrasonic wave to be 50kHz, and taking out the branch artware for standby after 50min of treatment;

(3) coating treatment:

uniformly coating the treating agent obtained in the step (1) on the surface of the branch artware subjected to surface activation treatment in the step (2);

(4) and (3) constant-temperature drying treatment:

and (4) drying the branch artware coated in the step (3) in a constant-temperature drying box at 65 ℃.

Example 4

A special anti-corrosion treatment process for branch artware comprises the following steps:

(1) preparation of the treating agent:

A. weighing 1.6 parts of natamycin, 0.8 part of lysozyme, 6 parts of carnauba wax, 3.5 parts of palmitic acid, 3.4 parts of glycerol monocaprylate, 2.7 parts of sodium sulfite, 6 parts of D-mannitol, 3 parts of calcium silicate, 2.5 parts of propylene glycol alginate and 95 parts of pure water in corresponding parts by weight for later use;

B. placing the carnauba wax, the palmitic acid, the glyceryl monocaprylate, the sodium sulfite, the D-mannitol, the calcium silicate, the propylene glycol alginate and the pure water which are weighed in the operation A into a homogenizer together for homogenization treatment, controlling the working pressure of the homogenizer to be 115MPa and the time to be 9L/h, and obtaining a mixture for later use after completion;

C. placing the mixture obtained in the operation A, the nisin, the natamycin, the lysozyme and the operation B in a stirring tank, and carrying out variable speed stirring treatment, wherein the mixture is stirred at 500rpm for 25min, then at 2500rpm for 10min, and then at 600rpm for 35 min;

(2) surface activation treatment:

placing the branch artware to be treated in an ultraviolet environment for ultraviolet irradiation treatment, wherein the distance between the highest point of the branch artware and an ultraviolet lamp is 3cm, carrying out ultrasonic treatment while irradiating the branch artware by ultraviolet light, controlling the frequency of the ultrasonic wave to be 40kHz, and taking out the branch artware for later use after 45min of treatment;

(3) coating treatment:

uniformly coating the treating agent obtained in the step (1) on the surface of the branch artware subjected to surface activation treatment in the step (2);

(4) and (3) constant-temperature drying treatment:

and (4) drying the branch artware coated in the step (3) in a constant-temperature drying box at 60 ℃.

Example 5

A special anti-corrosion treatment process for branch artware comprises the following steps:

(1) preparation of the treating agent:

A. weighing 4.5 parts of nisin, 0.8 part of lysozyme, 6 parts of carnauba wax, 3.5 parts of palmitic acid, 3.4 parts of glycerol monocaprylate, 2.7 parts of sodium sulfite, 6 parts of D-mannitol, 3 parts of calcium silicate, 2.5 parts of propylene glycol alginate and 95 parts of pure water in corresponding parts by weight for later use;

B. placing the carnauba wax, the palmitic acid, the glyceryl monocaprylate, the sodium sulfite, the D-mannitol, the calcium silicate, the propylene glycol alginate and the pure water which are weighed in the operation A into a homogenizer together for homogenization treatment, controlling the working pressure of the homogenizer to be 115MPa and the time to be 9L/h, and obtaining a mixture for later use after completion;

C. placing the mixture obtained in the operation A, the nisin, the natamycin, the lysozyme and the operation B in a stirring tank, and carrying out variable speed stirring treatment, wherein the mixture is stirred at 500rpm for 25min, then at 2500rpm for 10min, and then at 600rpm for 35 min;

(2) surface activation treatment:

placing the branch artware to be treated in an ultraviolet environment for ultraviolet irradiation treatment, wherein the distance between the highest point of the branch artware and an ultraviolet lamp is 3cm, carrying out ultrasonic treatment while irradiating the branch artware by ultraviolet light, controlling the frequency of the ultrasonic wave to be 40kHz, and taking out the branch artware for later use after 45min of treatment;

(3) coating treatment:

uniformly coating the treating agent obtained in the step (1) on the surface of the branch artware subjected to surface activation treatment in the step (2);

(4) and (3) constant-temperature drying treatment:

and (4) drying the branch artware coated in the step (3) in a constant-temperature drying box at 60 ℃.

Example 6

A special anti-corrosion treatment process for branch artware comprises the following steps:

(1) preparation of the treating agent:

A. weighing 4.5 parts of nisin, 1.6 parts of natamycin, 6 parts of carnauba wax, 3.5 parts of palmitic acid, 3.4 parts of glycerol monocaprylate, 2.7 parts of sodium sulfite, 6 parts of D-mannitol, 3 parts of calcium silicate, 2.5 parts of propylene glycol alginate and 95 parts of pure water in corresponding parts by weight for later use;

B. placing the carnauba wax, the palmitic acid, the glyceryl monocaprylate, the sodium sulfite, the D-mannitol, the calcium silicate, the propylene glycol alginate and the pure water which are weighed in the operation A into a homogenizer together for homogenization treatment, controlling the working pressure of the homogenizer to be 115MPa and the time to be 9L/h, and obtaining a mixture for later use after completion;

C. placing the mixture obtained in the operation A, the nisin, the natamycin, the lysozyme and the operation B in a stirring tank, and carrying out variable speed stirring treatment, wherein the mixture is stirred at 500rpm for 25min, then at 2500rpm for 10min, and then at 600rpm for 35 min;

(2) surface activation treatment:

placing the branch artware to be treated in an ultraviolet environment for ultraviolet irradiation treatment, wherein the distance between the highest point of the branch artware and an ultraviolet lamp is 3cm, carrying out ultrasonic treatment while irradiating the branch artware by ultraviolet light, controlling the frequency of the ultrasonic wave to be 40kHz, and taking out the branch artware for later use after 45min of treatment;

(3) coating treatment:

uniformly coating the treating agent obtained in the step (1) on the surface of the branch artware subjected to surface activation treatment in the step (2);

(4) and (3) constant-temperature drying treatment:

and (4) drying the branch artware coated in the step (3) in a constant-temperature drying box at 60 ℃.

Example 7

A special anti-corrosion treatment process for branch artware comprises the following steps:

(1) preparation of the treating agent:

A. weighing 6 parts of carnauba wax, 3.5 parts of palmitic acid, 3.4 parts of glyceryl monocaprylate, 2.7 parts of sodium sulfite, 6 parts of D-mannitol, 3 parts of calcium silicate, 2.5 parts of propylene glycol alginate and 95 parts of pure water in corresponding parts by weight for later use;

B. placing the carnauba wax, the palmitic acid, the glyceryl monocaprylate, the sodium sulfite, the D-mannitol, the calcium silicate, the propylene glycol alginate and the pure water which are weighed in the operation A into a homogenizer together for homogenization treatment, controlling the working pressure of the homogenizer to be 115MPa and the time to be 9L/h, and obtaining a mixture for later use after completion;

C. placing the mixture obtained in the operation A, the nisin, the natamycin, the lysozyme and the operation B in a stirring tank, and carrying out variable speed stirring treatment, wherein the mixture is stirred at 500rpm for 25min, then at 2500rpm for 10min, and then at 600rpm for 35 min;

(2) surface activation treatment:

placing the branch artware to be treated in an ultraviolet environment for ultraviolet irradiation treatment, wherein the distance between the highest point of the branch artware and an ultraviolet lamp is 3cm, carrying out ultrasonic treatment while irradiating the branch artware by ultraviolet light, controlling the frequency of the ultrasonic wave to be 40kHz, and taking out the branch artware for later use after 45min of treatment;

(3) coating treatment:

uniformly coating the treating agent obtained in the step (1) on the surface of the branch artware subjected to surface activation treatment in the step (2);

(4) and (3) constant-temperature drying treatment:

and (4) drying the branch artware coated in the step (3) in a constant-temperature drying box at 60 ℃.

Example 8

A special anti-corrosion treatment process for branch artware comprises the following steps:

(1) preparation of the treating agent:

A. weighing 4.5 parts of nisin, 1.6 parts of natamycin, 0.8 part of lysozyme, 6 parts of carnauba wax, 3.5 parts of palmitic acid, 3.4 parts of glycerol monocaprylate, 2.7 parts of sodium sulfite, 6 parts of D-mannitol, 3 parts of calcium silicate, 2.5 parts of propylene glycol alginate and 95 parts of pure water in corresponding parts by weight for later use;

B. placing the carnauba wax, the palmitic acid, the glyceryl monocaprylate, the sodium sulfite, the D-mannitol, the calcium silicate, the propylene glycol alginate and the pure water which are weighed in the operation A into a homogenizer together for homogenization treatment, controlling the working pressure of the homogenizer to be 115MPa and the time to be 9L/h, and obtaining a mixture for later use after completion;

C. placing the mixture obtained in the operation A, the nisin, the natamycin, the lysozyme and the operation B in a stirring tank, and carrying out variable speed stirring treatment, wherein the mixture is stirred at 500rpm for 25min, then at 2500rpm for 10min, and then at 600rpm for 35 min;

(2) coating treatment:

uniformly coating the treating agent obtained in the step (1) on the surface of the branch artware;

(3) and (3) constant-temperature drying treatment:

and (3) drying the branch artware coated in the step (2) in a constant-temperature drying box at 60 ℃.

In order to compare the technical effects of the application, the branch artware of the same specification and model produced in the same batch is selected as a test object, the selected branch artware is randomly divided into 7 groups with equal quality and quantity, wherein 6 groups are experimental groups, 1 group is a blank control group, then the branch artware of each experimental group is correspondingly processed by the methods of the embodiment 2 and the embodiment 4-8 respectively, after the test is finished, the mildew-proof corrosion resistance test is carried out, specifically, the branch artware (including the blank control group) of each group is placed in the environment with the temperature of 25-30 ℃ and the humidity of 65-75% respectively, the fungus infection area, the growth of the mildew and the surface corrosion condition of the branch artware of each group are observed visually after 6 weeks, the fungus infection area, the growth of the mildew and the surface corrosion condition are observed once every 4 weeks and recorded, the damage value is graded according to the table 1, the corrosion resistance effect is evaluated according to the comparison data of the specific test are shown in the following table 2:

TABLE 1

Rating of damage value	Area of moldy corrosion of each group of branch artware
		0	Area of surface mildew corrosion<5% of surface without hypha
1	The mildew corrosion area on the surface is 5-25%
		2	The mildew corrosion area on the surface is 25-0%
3	The mildew corrosion area on the surface is 50-75%
		4	Area of surface mildew corrosion>75％

TABLE 2

As can be seen from the table 1, the branch artware treated by the method has good lasting mildew-proof antibacterial property, and plays a good protection role on the branch artware, so that the corrosion resistance of the branch artware is enhanced, and the effect is obvious.

The above description is only for the purpose of illustrating the preferred embodiments of the present invention, and the present invention is not limited to the illustrated embodiments, and all the modifications and equivalents of the embodiments may be made without departing from the spirit of the present invention.