1. The production process of the white malleable cast iron is characterized by comprising the following steps:

s1, carrying out mixed smelting on the raw materials and additives to obtain high-carbon molten iron;

s2, casting high-carbon molten iron with proper temperature into a precoated sand shell, and cooling and forming to obtain a formed green body;

s3, trimming burrs and gates of the molded green bodies;

s4, performing decarburization annealing treatment on the trimmed green body to obtain a casting;

and S5, performing deburring and shot blasting treatment on the casting.

2. The process for producing white malleable cast iron, according to claim 1, wherein the decarburization annealing in step S4 is divided into the following steps:

s41, carrying out first heat treatment on the mixed material, wherein the first heat treatment temperature is 1050 ℃ and the time duration is 45-50 h;

s42, carrying out secondary heat treatment on the mixed material, wherein the temperature is gradually reduced from 1050 ℃ to 750 ℃ according to the temperature difference of 100 ℃, the temperature is preserved for 4 hours after each temperature reduction, and the temperature reduction rate of each step is less than or equal to 12 ℃/h.

3. The process for producing white malleable cast iron, as claimed in claim 2, wherein the first heat treatment in step S41 further comprises 2-4 temperature changes from 1050 ℃ to 900 ℃ and then from 1050 ℃ to 1050 ℃.

4. Process for the production of white malleable cast iron, according to claim 1,

in the step S1, the raw materials are scrap steel and foundry returns, and the additives are 60-70% of ferromanganese and 92-98% of carburant;

the decarburization materials in the decarburization annealing in step S4 are ferron and iron ore.

5. The process for producing white ductile cast iron according to claim 1, wherein the sand-coated shell mold of step S2 is obtained by sand shooting into a mold using a core shooting machine.

6. The production process of the white heart malleable cast iron, according to the claim 5, characterized in that, the core shooter includes the sand hopper (1), the bottom of the sand hopper (1) is equipped with the sand shooting organization (2), the mould includes the stationary mould (3) and moving mould (4), the moving mould (4) after moving horizontally closes the mould with the stationary mould (3),

penetrate sand mechanism (2) and include columniform and hold set (5), hold set (5) and rotate in vertical direction, the side that holds set (5) evenly is provided with a plurality of shower nozzles (6), shower nozzle (6) remove the setting and are in the mould top, the middle part that holds set (5) is provided with first cavity (7), first cavity (7) periphery to distribute have a plurality of second cavities (8), every second cavity (8) one end with first cavity (7) intercommunication, the other end with shower nozzle (6) intercommunication.

7. Process for the production of white malleable cast iron, according to the claim 5, characterized by the fact that inside the sprinkler head (6) there is a rotating ball (9), on which (9) there is a through hole, which communicates with the sprinkler head (6) after the rotation of the rotating ball (9).

8. The production process of the white malleable cast iron, according to the claim 6, characterized in that the outside of the nozzle (6) is equipped with the rotating rod (10), the rotating rod (10) vertically passes through the nozzle (6) and then connects with the rotating ball (9),

a fan-shaped rotary table (11) is arranged outside the spray head (6), the fan-shaped rotary table (11) is arranged on the containing disc (5), an arc-shaped rack (12) is arranged on the arc-shaped edge of the fan-shaped rotary table (11) in a sliding manner, a circular gear (13) meshed with the arc-shaped rack (12) is arranged on one side of the fan-shaped rotary table (11), the circular gear (13) is coaxially connected with the rotating rod (10),

the fan-shaped rotary table (11) is hinged with a first connecting rod (14), a second connecting rod (15) is arranged at the free end of the first connecting rod (14), and the second connecting rod (15) is connected with an output shaft of the motor.

9. The process for producing white heart malleable cast iron, according to the claim 2, characterized in that the joint of the moving die (4) and the fixed die (3) is provided with a through hole which is circular after being pieced together and is communicated with the internal cavity, the nozzle (6) is inserted into the through hole to carry out sand blasting;

the movable mould (4) with be provided with first buckling parts (16) and second buckling parts (17) on cover half (3) lateral wall respectively, first buckling parts (16) with second buckling parts (17) are followed movable mould (4) with form calibration mechanism after cover half (3) amalgamation.

Background

The white-core malleable cast iron has a non-uniform surface and inner structure, an outer layer of fully ferritic, a central part of pearlitic and a small amount of flocculent graphite, and even residual free cementite. It has good mechanical property and weldability. Because of the particularity of the white heart malleable cast iron, the existing common cast iron production process is not suitable for the production of the white heart malleable cast iron, and a new process is needed to obtain a product meeting the carbon content requirement.

Disclosure of Invention

The invention provides a production process of white heart malleable cast iron, which solves the problem that the traditional process in the related technology is not suitable for producing the white heart malleable cast iron.

The technical scheme of the invention is as follows:

the production process of the white malleable cast iron comprises the following steps:

s1, carrying out mixed smelting on the raw materials and additives to obtain high-carbon molten iron;

s2, casting high-carbon molten iron with proper temperature into a precoated sand shell, and cooling and forming to obtain a formed green body;

s3, trimming burrs and gates of the molded green bodies;

s4, performing decarburization annealing treatment on the trimmed green body to obtain a casting;

and S5, performing deburring and shot blasting treatment on the casting.

The decarburization annealing in step S4 is divided into the following steps:

s41, carrying out first heat treatment on the mixed material, wherein the first heat treatment temperature is 1050 ℃ and the time duration is 45-50 h;

s42, carrying out secondary heat treatment on the mixed material, wherein the temperature is gradually reduced from 1050 ℃ to 750 ℃ according to the temperature difference of 100 ℃, the temperature is preserved for 4 hours after each temperature reduction, and the temperature reduction rate of each step is less than or equal to 12 ℃/h.

Wherein, the first heat treatment in step S41 further includes 2-4 temperature changes from 1050 ℃ to 900 ℃ and then from 1050 ℃ to 1050 ℃.

In the step S1, the raw materials are scrap steel and foundry returns, and the additives are 60-70% of ferromanganese and 92-98% of carburant;

the decarburization materials in the decarburization annealing in step S4 are ferron and iron ore.

The sand-coated shell mold in step S2 is obtained by shooting sand into a mold using a core shooter.

The core shooter comprises a sand hopper, a sand shooting mechanism is arranged at the bottom of the sand hopper, the mould comprises a fixed mould and a movable mould, the movable mould is horizontally moved and then matched with the fixed mould,

penetrate sand mechanism and include that the columniform holds the dish, hold the dish and rotate in vertical direction, the side that holds the dish evenly is provided with a plurality of shower nozzles, the shower nozzle removes to set up the mould top, the middle part that holds the dish is provided with first cavity, first cavity periphery distributes has a plurality of second cavities, every second cavity one end with first cavity intercommunication, the other end with the shower nozzle intercommunication.

The nozzle is characterized in that a rotating ball is arranged in the nozzle, a through hole is formed in the rotating ball, and the through hole is communicated with the nozzle after the rotating ball rotates.

A rotating rod is arranged outside the spray head and vertically penetrates through the spray head to be connected with the rotating ball,

a fan-shaped rotary table is arranged outside the spray head, the fan-shaped rotary table is arranged on the containing disc, an arc-shaped rack is arranged on the arc-shaped edge of the fan-shaped rotary table in a sliding manner, a circular gear meshed with the arc-shaped rack is arranged on one side of the fan-shaped rotary table, the circular gear is coaxially connected with the rotating rod,

the fan-shaped rotary table is hinged with a first connecting rod, the free end of the first connecting rod is provided with a second connecting rod, and the second connecting rod is connected with an output shaft of the motor.

A through hole which is in a circular shape after being spliced is formed in the joint of the movable mold and the fixed mold and is communicated with an internal cavity, and the spray head is inserted into the through hole for sand blasting;

the movable mould with be provided with first buckling parts and second buckling parts on the cover half lateral wall respectively, first buckling parts with the second buckling parts is followed form alignment mechanism after the movable mould with the cover half amalgamation.

The working principle and the beneficial effects of the invention are as follows:

1. in the invention, the target carbon content is below 0.3%, the high-temperature heat preservation time needs to be more than 45 hours (the lower the high-temperature heat preservation temperature is, the longer the heat preservation time is), and the C content below 2mm on the surface of the workpiece can reach 0.3%. However, the excessively long heat preservation time can cause severe oxidation of the parts, and the absolute high-temperature heat preservation time is between 45 and 50 hours in comprehensive consideration. After the high-temperature decarburization stage is finished, the temperature should not be rapidly reduced, and the toughness and the plasticity of the product are reduced due to an excessively high temperature reduction rate. The temperature reduction rate of not higher than 12 ℃ per hour needs to be kept, and the furnace can be opened and the workpiece can be taken out when the temperature reaches 750 ℃.

Drawings

The present invention will be described in further detail with reference to the accompanying drawings and specific embodiments.

FIG. 1 is a schematic side view of the present invention;

FIG. 2 is a schematic front view of the present invention;

FIG. 3 is an enlarged schematic view of the structure at the position A of the present invention;

FIG. 4 is a schematic view of a rotating ball according to the present invention;

FIG. 5 is a schematic structural view of a sector turntable according to the present invention;

FIG. 6 is a schematic view of the mold of the present invention;

FIG. 7 is a schematic diagram of a touch state structure of a buffer board according to the present invention;

FIG. 8 is a schematic diagram of a calibrated structure according to the present invention;

FIG. 9 is a schematic view of the structure of the retractable needle and the groove of the present invention;

in the figure: 1-a sand hopper, 2-a sand shooting mechanism, 3-a fixed die, 4-a movable die, 5-a containing disc, 6-a spray head, 7-a first cavity, 8-a second cavity, 9-a rotating ball, 10-a rotating rod, 11-a sector rotating disc, 12-an arc rack, 13-a circular gear, 14-a first connecting rod, 15-a second connecting rod, 16-a first buckling part, 17-a second buckling part, 18-a first fixing block, 19-a telescopic thimble, 20-a second fixing block, 21-a containing channel, 22-a buffer plate, 23-a half gear, 24-a straight rack and 25-a groove.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any inventive step, are intended to be within the scope of the present invention.

As shown in fig. 1 to 9, the present embodiment proposes a process for producing white heart malleable cast iron, comprising the steps of:

s1, carrying out mixed smelting on the raw materials and additives to obtain high-carbon molten iron;

s2, casting high-carbon molten iron with proper temperature into a precoated sand shell, and cooling and forming to obtain a formed green body;

s3, trimming burrs and gates of the molded green bodies;

s4, performing decarburization annealing treatment on the trimmed green body to obtain a casting;

and S5, performing deburring and shot blasting treatment on the casting.

Further, the decarburization annealing in step S4 is divided into the following steps:

s41, carrying out first heat treatment on the mixed material, wherein the first heat treatment temperature is 1050 ℃ and the time duration is 45-50 h;

s42, carrying out secondary heat treatment on the mixed material, wherein the temperature is gradually reduced from 1050 ℃ to 750 ℃ according to the temperature difference of 100 ℃, the temperature is preserved for 4 hours after each temperature reduction, and the temperature reduction rate of each step is less than or equal to 12 ℃/h.

In this embodiment, the target carbon content is less than 0.3%, the high-temperature heat preservation time needs to be more than 45 hours (the lower the high-temperature heat preservation temperature is, the longer the heat preservation time is), and the C content below 2mm on the surface of the workpiece can reach 0.3%. However, the excessively long heat preservation time can cause severe oxidation of the parts, and the absolute high-temperature heat preservation time is between 45 and 50 hours in comprehensive consideration. After the high-temperature decarburization stage is finished, the temperature should not be rapidly reduced, and the toughness and the plasticity of the product are reduced due to an excessively high temperature reduction rate. The temperature reduction rate of not higher than 12 ℃ per hour needs to be kept, and the furnace can be opened and the workpiece can be taken out when the temperature reaches 750 ℃.

Further, the first heat treatment in step S41 further includes 2-4 temperature changes from 1050 ℃ to 900 ℃ and then from 1050 ℃ to 1050 ℃.

In the embodiment, the temperature is slowly reduced to about 900 ℃ in a step shape during the high temperature period, and then is increased to about 1050 ℃ for 3 times, so that the carbon potential accumulation in the decarburization process is facilitated, and the decarburization efficiency is improved.

Further, in the step S1, the raw materials are scrap steel and foundry returns, and the additives are 60-70% of ferromanganese and 92-98% of carburant; the decarburization materials in the decarburization annealing in step S4 are ferron and iron ore.

In this example, the main component of iron is iron oxide.

Further, the sand-coated shell mold in step S2 is obtained by shooting sand into a mold using a core shooter.

Further, the core shooting machine comprises a sand hopper 1, a sand shooting mechanism 2 is arranged at the bottom of the sand hopper 1, the mold comprises a fixed mold 3 and a movable mold 4, the movable mold 4 is horizontally moved and then matched with the fixed mold 3,

penetrate sand mechanism 2 and include that the columniform holds set 5, hold set 5 and rotate in vertical direction, the side that holds set 5 evenly is provided with a plurality of shower nozzles 6, and shower nozzle 6 removes to set up in the mould top, and the middle part that holds set 5 is provided with first cavity 7, and 7 peripheral direction distributions of first cavity have a plurality of second cavities 8, 8 one ends of every second cavity and first cavity 7 intercommunication, the other end and shower nozzle 6 intercommunication.

In this embodiment, the existing sand shooting mechanism 2 generally has only one sand shooting nozzle 6, the sand shooting nozzle 6 is inserted into a sand injection hole on a mold for sand blasting, and the mold needs high temperature to solidify sand, so the sand shooting nozzle 6 with too close distance can cause the sand inside the nozzle 6 to be solidified, the nozzle 6 is easily blocked, and the sand blasting effect is affected. In this application, use pivoted to hold set 5, set up a plurality of shower nozzles 6, after once annotating the sand and accomplishing, rotate certain angle and make next shower nozzle 6 annotate the sand, shower nozzle 6 rotates the round and just can continue to annotate the sand, can carry out abundant cooling to shower nozzle 6, avoids long-time accumulation to be heated the solidification condition that leads to more and more serious. During the use, 1 below intercommunication of sand hopper holds first cavity 7 at dish 5 middle part, and the sand of first cavity 7 falls along being in the second cavity 8 whereabouts of below, gets into the mould sandblast through shower nozzle 6, then rotates certain angle, carries out work by next second cavity 8 and shower nozzle 6. Due to cooling and inversion of the spray head 6 which rotates to the upper part, the residual sand can fall into the first cavity 7 under the action of gravity, so that the spray head 6 is prevented from being blocked, and waste of the sand is also avoided.

Further, a rotating ball 9 is arranged in the nozzle 6, a through hole is formed in the rotating ball 9, and the through hole is communicated with the nozzle 6 after the rotating ball 9 rotates.

In this embodiment, set up a rolling ball 9 in every shower nozzle 6, be located and hold 5 during the below, rolling ball 9 rotates certain angle and makes through-hole and shower nozzle 6 communicate, thereby make sand spout, after once the sandblast is accomplished, 6 position changes of shower nozzle, rolling ball 9 also rotates certain angle and makes through-hole and shower nozzle 6 not communicate, block up shower nozzle 6, can avoid like this letting in the air current and drive sand spun simultaneously, make the sand in other inoperative second cavities 8 spout along shower nozzle 6, produce material waste and dust pollution on every side.

Furthermore, a rotating rod 10 is arranged outside the spray head 6, the rotating rod 10 vertically penetrates through the spray head 6 and then is connected with the rotating ball 9,

a fan-shaped rotating disk 11 is arranged outside the spray head 6, the fan-shaped rotating disk 11 is arranged on the accommodating disk 5, an arc-shaped rack 12 is arranged on the arc-shaped edge of the fan-shaped rotating disk 11 in a sliding way, a circular gear 13 meshed with the arc-shaped rack 12 is arranged on one side of the fan-shaped rotating disk 11, the circular gear 13 is coaxially connected with the rotating rod 10,

the sector rotary table 11 is hinged with a first connecting rod 14, the free end of the first connecting rod 14 is provided with a second connecting rod 15, and the second connecting rod 15 is connected with an output shaft of the motor.

In this embodiment, the rotating rod 10 drives the rotating ball 9 to rotate, the rack above the sector rotary disk 11 is meshed with the coaxial circular gear 13 on the rotating rod 10, the length of the arc rack 12 is smaller than that of the arc edge of the sector rotary disk 11, the two ends of the arc edge of the sector rotary disk 11 are provided with the stoppers, the first connecting rod 14 and the second connecting rod 15 are used for driving the sector rotary disk 11 to swing, and if the initial position of the arc rack 12 is in the middle of the sector rotary disk 11, the sector rotary disk 11 is also symmetrically arranged on two sides, after the operation, after the sector turntable 11 rotates clockwise for a certain angle, the left stop dog contacts the arc-shaped rack 12, and the stop dog drives the arc-shaped rack 12 to move clockwise along with the continuous clockwise rotation of the sector turntable 11, at the moment, the circular gear 13 also rotates, the distance between the right end of the arc-shaped rack 12 and the stop dog at the right end of the sector turntable 11 is increased, and therefore the angle of the rotating ball 9 is adjusted; when the sector turntable 11 starts to rotate anticlockwise, the rack is not moved before the stop block at the right end of the sector turntable 11 touches the rack, the circular gear 13 is not moved, and the sector turntable 11 and the circular gear rotate reversely after touching the arc rack 12, so that the rotating ball 9 is adjusted.

Furthermore, a through hole which is circular after being spliced is arranged at the joint of the movable mold 4 and the fixed mold 3 and is communicated with an internal cavity, and the spray head 6 is inserted into the through hole for sand blasting;

the side walls of the movable mold 4 and the fixed mold 3 are respectively provided with a first buckling part 16 and a second buckling part 17, and the first buckling part 16 and the second buckling part 17 form a calibration mechanism after the movable mold 4 and the fixed mold 3 are spliced.

In the embodiment, the existing die assembly of the fixed die 3 and the movable die 4 is realized by utilizing a slide bar to enable the movable die 4 to move towards the fixed die 3, but the slide bar is generally thick, the precision is low, the die assembly is possibly inaccurate due to long-time use, relative dislocation is generated between the movable die 4 and the fixed die 3, the sealing performance of the die is influenced, and further the product quality is influenced. Therefore, the calibration mechanism is arranged, and the mold clamping precision is improved.

Further, the first engaging portion 16 includes

A first fixed block 18, a telescopic thimble 19 is arranged on the side surface of the first fixed block 18 facing to a second fixed block 20,

the second engaging portion 17 includes

A second fixed block 20, wherein the side surface of the second fixed block 20 facing the first fixed block 18 is provided with a containing channel 21, the telescopic thimble 19 is inserted into the containing channel 21,

the first fixing block 18 and the second fixing block 20 are rotatably provided with buffer plates 22.

In this embodiment, during the compound die, two buffer boards 22 set up relatively, at first two buffer boards 22 produce the contact collision, give certain buffering, then buffer board 22 contact back, the sensor received signal makes drive arrangement drive buffer board 22 upset 90, the drive arrangement here can be multiple current common drive arrangement such as cylinder hydro-cylinder, buffer board 22 upset back, expose first fixed block 18 and second fixed block 20, at this moment, because there is not buffer board 22 to the effect of blockking of flexible thimble 19, flexible thimble 19 stretches out and inserts under the spring action and holds in the passageway 21, realize the position correction of cover half 3 and movable mould 4. The size of the end part of the thimble is far smaller than the inner diameter of the containing channel 21, even if the fixed die 3 and the movable die 4 are not aligned in the initial die assembly stage, the thimble can conveniently enter the containing channel 21, then, the thimble can only enter a unique position along a unique path due to the stepped shape of the thimble and the double limitation and interaction of the inner groove 25 of the containing channel 21, the dislocation caused by the misalignment can be gradually corrected in the entering process, finally, the thimble is inserted into the innermost part of the containing channel 21, the fixed die 3 and the movable die 4 also realize position calibration, and then, the sand blasting operation is carried out.

Further, a half gear 23 is provided on the rotation shaft of the buffer plate 22, and a spur rack 24 meshing with the half gear 23 is provided on one side of the half gear 23.

In this embodiment, the 90-degree turnover of the buffer plate 22 is realized by the spur rack 24 and the half gear 23. The buffer plate 22 is connected with the rotating shaft through a connecting rod.

Further, the maximum diameter of the ejector pin is greater than the maximum inner diameter of the accommodating channel 21, the ejector pin comprises a first step portion, a second step portion, a third step portion and a head portion which are connected in sequence, wherein the convex edges of the third step portion and the head portion are in arc transition, the ejector pin is integrally in a step shape, the outer diameter of the ejector pin is gradually reduced, and a groove 25 matched with the ejector pin in shape is formed in the accommodating channel 21.

In this embodiment, the diameter of the accommodating channel 21 is smaller than the maximum outer diameter of the thimble, and the thimble can be gradually clamped after being inserted into the accommodating channel 21, the cross sections of the first step portion and the second step portion are the same, that is, the first step portion and the second step portion are cylindrical and are used for being tightly connected with the side wall of the channel, the third step portion and the fourth step portion are both in a shape of gradually reduced outer diameter, and the edge is arc-shaped and is used for applying pressure to the thimble along the arc-shaped edge when the buffer plate 22 is retracted, so that the thimble is retracted, the arc-shaped edge facilitates smooth contact retraction on the one hand, and on the other hand, the thimble is not easily damaged.

The present invention is not limited to the above preferred embodiments, and any modifications, equivalent substitutions, improvements, etc. within the spirit and principle of the present invention should be included in the protection scope of the present invention.